ZHOU Qingye, LU Xiushan, SONG Moudao, ZHANG Banghua, HAO Guangjie, ZHANG Ying, HE Binglin. THE INFLUENCES OF PVP ON THE PROPERTIES OF THE CONDENSATION POLYMERS MEMBRANE OF DIBENZO-18-CROWN-6 WITH SEBACIC ACID[J]. Acta Polymerica Sinica, 1999,(3):315-319.
ZHOU Qingye, LU Xiushan, SONG Moudao, ZHANG Banghua, HAO Guangjie, ZHANG Ying, HE Binglin. THE INFLUENCES OF PVP ON THE PROPERTIES OF THE CONDENSATION POLYMERS MEMBRANE OF DIBENZO-18-CROWN-6 WITH SEBACIC ACID[J]. Acta Polymerica Sinica, 1999,(3):315-319.DOI:
The high molecular weight condensation polymers(CEP-1) of dibenzo-18-crown-6(DB-18-C-6) with sebacic acid were good membrane-forming material
which had higher complex selectivities to K+
but the permeabilities of the membranes were low.The permeabilities can be improved greatly when CEP-1 was mixed with a little water-soluble poly(vinyl pyrrolidone)(PVP).The experimental result showed that CEP-1/PVP membranes have high complex rate
complex ability
complex selectivity to K+.The DMA spectra indicated that the modulus[E] and tangent of the loss angle(tanδ)
were changed
therefore the CEP-1/PVP blends were partially compatible system.It has been found that the amount of PVP dissolved from CEP-1/PVP membrane were increased with temoerature of water solution raising.