A new series of the ligands of liquid crystal polymers with T-shaped two-dimensionl mesogens was synthesied by solution condensation polymerization by using 4

4'-(

-alkylenedioyloxy)-dibenzol dichlorids with 2

4-dihydroxy-4]'-alkoxyl azobenzene as the monomers. The low molecular weight compounds were analyzed by elementary analysis

IR

1H-NMR and MS. The ligands were characterized by GPC

DSC

TG

WAXD and polarizing microscopy with a heating stage. It was found that all the ligand of polymers went to liquid crystal phase when heated to their Tm

the threaded texture ands schlieren texture can be observed.Both Tmand Ti of all the ligands change regulary with the increase of the end alkoxy group length and when the flexible spacer unit in the ligand gets longer.It is worth specially being noted that some of the ligands having no end substituent groups were also found to show liquid crystal behaviors

which would be a new subject for further research on the formation mechanism and the texture of such kind of the ligands.