热开环聚合制备高分子量二茂铁基聚二甲基硅烷及其与四氰基乙烯生成电荷转移络合物的研究

王立; 潘杰; 计兵; 封麟先

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热开环聚合制备高分子量二茂铁基聚二甲基硅烷及其与四氰基乙烯生成电荷转移络合物的研究

研究简报 | 更新时间：2021-03-19

- 热开环聚合制备高分子量二茂铁基聚二甲基硅烷及其与四氰基乙烯生成电荷转移络合物的研究
- STUDY ON THE PREPARATION OF HIGH MOLECULAR WEIGHT POLY(FERROCENYL DIMETHYLSILANE) THROUGH THERMAL RING OPENING POLYMERIZATION AND POLY(FERROCENYLDIMETHYLSILANE)/TCNE CHARGE TRANSFER COMPLEX
- 高分子学报 2000年第6期页码：788-790
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- 纸质出版日期：2000-12-20，
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王立, 潘杰, 计兵, 封麟先. 热开环聚合制备高分子量二茂铁基聚二甲基硅烷及其与四氰基乙烯生成电荷转移络合物的研究[J]. 高分子学报, 2000,(6):788-790.

WANG Li, PAN Jie, JI Bing, FENG Linxian. STUDY ON THE PREPARATION OF HIGH MOLECULAR WEIGHT POLY(FERROCENYL DIMETHYLSILANE) THROUGH THERMAL RING OPENING POLYMERIZATION AND POLY(FERROCENYLDIMETHYLSILANE)/TCNE CHARGE TRANSFER COMPLEX[J]. Acta Polymerica Sinica, 2000,(6):788-790.
王立, 潘杰, 计兵, 封麟先. 热开环聚合制备高分子量二茂铁基聚二甲基硅烷及其与四氰基乙烯生成电荷转移络合物的研究[J]. 高分子学报, 2000,(6):788-790. DOI：

WANG Li, PAN Jie, JI Bing, FENG Linxian. STUDY ON THE PREPARATION OF HIGH MOLECULAR WEIGHT POLY(FERROCENYL DIMETHYLSILANE) THROUGH THERMAL RING OPENING POLYMERIZATION AND POLY(FERROCENYLDIMETHYLSILANE)/TCNE CHARGE TRANSFER COMPLEX[J]. Acta Polymerica Sinica, 2000,(6):788-790. DOI：

摘要

Abstract

Ferrocenediyldimethylsilane monomer has been synthesized.A series of poly(ferrocenyl dimethylsilanes) with different molecular weights have been prepared by thermal ring\|opening polymerization of 1

1′-Ferrocenediyldimethylsilane at different polymerization time. It was found that with increasing polymerization time from 5min to 60min the molecular weights of resultant poly(ferrocenyl dimethylsilanes) increase from Mn=1.7×104 to Mn=1.7×105. The reactions of ferrocene with tetracyanoethylene (TCNE) and the reactions of poly(ferrocenyl dimethylsilanes) with tetracyanoethylene (TCNE) were investigated by ESR. A signal with g≈2 was detected from resultant poly (ferrocenyl dimethylsilane)/TCNE system

which indicates the formation of poly (ferrocenyl dimethylsiliane)/TCNE charge transfer complex.

关键词

热开环聚合二茂铁基聚二甲基硅烷四氰基乙烯电荷转移络合物

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