JIANG Yong, DING Enyong, LI Guokang. RELATIONSHIPS BETWEEN COMPOSITION AND ENERGY STORAGE PROPERTIES FOR CROSSLINKED PHASE CHANGE MATERIALS PREPARED FROM PEG/CDA[J]. Acta Polymerica Sinica, 2000,(6):681-687.
JIANG Yong, DING Enyong, LI Guokang. RELATIONSHIPS BETWEEN COMPOSITION AND ENERGY STORAGE PROPERTIES FOR CROSSLINKED PHASE CHANGE MATERIALS PREPARED FROM PEG/CDA[J]. Acta Polymerica Sinica, 2000,(6):681-687.DOI:
New kinds of solid-solid phase change materials(PCMs) with netted structure have been prepared.In these materials
a flexible polymer PEG (polyethylene glycol) has been taken as functional branches
with which the energy storage and energy release can be proceeded by phase transition between its crystal state and amorphous state.And a rigid polymer CDA (cellulose diacetate) has been taken as skeleton
which ensures the solid-nature of PCMs during the phase transition.IR
X-ray
TG
DSC
TEM
polarizing microscopy and so on were used to study the structure and properties of PCMs.The former studies showed that these new PCMs have typical colid-solid phase transformation property
quite good energy storage effect and have better thermal stability.In this paper
the effects of molecular weight and weight percentage of PEG in composition on energy storage properties were discussed in detail.The results showed that PEG in composition on energy storage properties were discussed in detail.The results showed that PCMs with different latent heat
different phase transition temperature and different mechanical strength can be obtained by means of modifying the molecular weight and weight percentage of PEG.