CHEN Ruizhu, ZHANG Ying, ZHANG Yuncan, PAN Enli, OU Yuchun, YU Zhongzhen. SYNTHESIS AND CHARACTERIZATION OF GRAFT COPOLYMER OF EAA WITH POLY(2-ETHYL-2-OXAZOLINE)[J]. Acta Polymerica Sinica, 2000,(2):200-204.
CHEN Ruizhu, ZHANG Ying, ZHANG Yuncan, PAN Enli, OU Yuchun, YU Zhongzhen. SYNTHESIS AND CHARACTERIZATION OF GRAFT COPOLYMER OF EAA WITH POLY(2-ETHYL-2-OXAZOLINE)[J]. Acta Polymerica Sinica, 2000,(2):200-204.DOI:
The title graft copolymer was synthesized by a two-step polymerization process. In the first step the monomer of 2-ethyl-2-oxazoline (EOX) was polymerized by cationic ring-opening polymerization with MeOTs as initiator in toluene. The prepolymer of poly(N-propionyl-ethylenimine) (PEOX) having living propagating end of oxazolinium ion in toluene was obtained with average molecular weight less than 10
000g/mol .Then the EAA (ethylene-acrylic acid copolymer) was grafted through the reaction of pendant carboxy group of EAA with the terminated living oxazolinium ion of PEOX in toluene.The effect of various parameters such as reaction condition of cationic polymerization
grafting reaction time and temperature
reactive group in EAA and PEOX molar ratio
and carboxy group content in EAA on grafting degree and average degree of polymerization in the graft chain were evaluated.It was found that there was a maximum grafting degree of graft copolymers
when the EAA/PEOX molar ratio is in the range of 5~6.The graft copolymer EAA-g-PEOX with grafting degree>25% can be obtained under some specific conditions
such copolymer can be used as compatiblizer in PBT/PP blends to improve the compatibility of the two phases and the mechanical properties.