ZHEN Zhen, TANG Junhui, WANG Dongjun, TANG Daihua, WANG Xiaobing, WANG Fengqi, LIU Xinhou. THE EFFECTS OF POLYMERIZATION CONDITIONS ON THE REFRACTIVE INDEX PROFILE OF THE PREFORM ROD[J]. Acta Polymerica Sinica, 2000,(2):153-156.
ZHEN Zhen, TANG Junhui, WANG Dongjun, TANG Daihua, WANG Xiaobing, WANG Fengqi, LIU Xinhou. THE EFFECTS OF POLYMERIZATION CONDITIONS ON THE REFRACTIVE INDEX PROFILE OF THE PREFORM ROD[J]. Acta Polymerica Sinica, 2000,(2):153-156.DOI:
Plastic rods with gradient refractive index were successfully fabricated by the interfacial-gel polymerization technique
in which two kinds of dopants were used for their higher refractive index and different molecular volume.The effects of dopant concentration
the molecular volume and the temperature of polymerization on the refractive index profile of the preform rods were investigated in detail.Experimental results showed that the difference of the refractive index between the center and the periphery of the preform rod increased with increasing temperature due to the increase of the gel effect and polymerization rate at a higher temperature.The parabolic refractive index ditribution was slightly flatted at lower temperature mainly due to decreasing rate of polymerization
therefore there is more time for the dopants to diffuse into the gel.