HOU Si-jian, HA Run-hua. STUDIES ON KINETICS OF INVERSE EMULSION COPOLYMERIZATION OF DIALLYLDIMETHYL AMMONIUM CHLORIDE AND ACRYLAMIDE[J]. Acta Polymerica Sinica, 1995,(3):349-354.
HOU Si-jian, HA Run-hua. STUDIES ON KINETICS OF INVERSE EMULSION COPOLYMERIZATION OF DIALLYLDIMETHYL AMMONIUM CHLORIDE AND ACRYLAMIDE[J]. Acta Polymerica Sinica, 1995,(3):349-354.DOI:
sing SPAN-OP composite emulsifier and K2S2O8-Na2SO3 redox initiator
the inverse emulsion copolymerization of diallyldimethyl ammoniumchloride (DADMAC) and acrylamide (AM) was developed. The monomer reactivity ratios are γDADMAC=0.14±0.11
γAM=5.05±0.66; Under the conditions of total concentration of monomer being 25-45%
initiator concentration being 0.06-0.1%
emulsifier concentration being 5-9% and polymerization temperature being 303K
the kinetic equation of copolymerization can be expressed: Rp=k[M]0.68[I]1.31[E]0.73. In this paper