含胺基功能性单体的聚合研究——Ⅲ.甲基丙烯酸4-(N,N-二甲氨基)苄酯在过氧化月桂酰引发下的聚合动力学

李福绵; 叶卫平; 冯新德

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含胺基功能性单体的聚合研究——Ⅲ.甲基丙烯酸4-(N,N-二甲氨基)苄酯在过氧化月桂酰引发下的聚合动力学

研究简报 | 更新时间：2021-03-19

- 含胺基功能性单体的聚合研究——Ⅲ.甲基丙烯酸4-(N,N-二甲氨基)苄酯在过氧化月桂酰引发下的聚合动力学
- STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO GROUPS——Ⅲ. Polymerization of 4-(N, N-Dimethylaminobenzyl) Methacrylate Initiated by Lauroyl Peroxide
- 高分子学报 1982年第5期页码：397-400
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- 纸质出版日期：1982-10-20，
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李福绵, 叶卫平, 冯新德. 含胺基功能性单体的聚合研究——Ⅲ.甲基丙烯酸4-(N,N-二甲氨基)苄酯在过氧化月桂酰引发下的聚合动力学[J]. 高分子学报, 1982,(5):397-400.

LI Fu-mian, Ye Wei-peng, FENG Xin-de. STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO GROUPS——Ⅲ. Polymerization of 4-(N, N-Dimethylaminobenzyl) Methacrylate Initiated by Lauroyl Peroxide[J]. Acta Polymerica Sinica, 1982,(5):397-400.
李福绵, 叶卫平, 冯新德. 含胺基功能性单体的聚合研究——Ⅲ.甲基丙烯酸4-(N,N-二甲氨基)苄酯在过氧化月桂酰引发下的聚合动力学[J]. 高分子学报, 1982,(5):397-400. DOI：

LI Fu-mian, Ye Wei-peng, FENG Xin-de. STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO GROUPS——Ⅲ. Polymerization of 4-(N, N-Dimethylaminobenzyl) Methacrylate Initiated by Lauroyl Peroxide[J]. Acta Polymerica Sinica, 1982,(5):397-400. DOI：

摘要

Abstract

Polymerization of 4-(N

N-dimethylaminobenzyl)methacrylate (DMABMA) initiated by LPO has been studied. The rate equation of the polymerization which was determined at 20

40 and 50℃ was found to be Rp=Kp [DMABMA]1.5 [LPO]0.5

and the overall activation energy of this polymerization system was determined as 12.2 Kcal/mol. Owing to the above results and the monomer containing tertiary aromatic amino group

the redox nature of LPO with the monomer itself has been suggested.

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