2-苯基-4-亚甲基-1,3-二氧环戊烷与受电子单体的自动共聚反应

潘才元; 邬征

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2-苯基-4-亚甲基-1,3-二氧环戊烷与受电子单体的自动共聚反应

研究简报 | 更新时间：2021-03-19

- 2-苯基-4-亚甲基-1,3-二氧环戊烷与受电子单体的自动共聚反应
- SPONTANEOUS COPOLYMERIZATION OF 2-PHENYL-4-METHYLENE-l,3-DIOXOLANE WITH ELECTRON-DEFICIENT VINYL MONOMERS
- 高分子学报 1988年第1期页码：76-80
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- 纸质出版日期：1988-2-20，
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潘才元, 邬征. 2-苯基-4-亚甲基-1,3-二氧环戊烷与受电子单体的自动共聚反应[J]. 高分子学报, 1988,(1):76-80.

PAN Cai-yuan, WU Zheng. SPONTANEOUS COPOLYMERIZATION OF 2-PHENYL-4-METHYLENE-l,3-DIOXOLANE WITH ELECTRON-DEFICIENT VINYL MONOMERS[J]. Acta Polymerica Sinica, 1988,(1):76-80.
潘才元, 邬征. 2-苯基-4-亚甲基-1,3-二氧环戊烷与受电子单体的自动共聚反应[J]. 高分子学报, 1988,(1):76-80. DOI：

PAN Cai-yuan, WU Zheng. SPONTANEOUS COPOLYMERIZATION OF 2-PHENYL-4-METHYLENE-l,3-DIOXOLANE WITH ELECTRON-DEFICIENT VINYL MONOMERS[J]. Acta Polymerica Sinica, 1988,(1):76-80. DOI：

摘要

Abstract

2-Phenyl-4-methylene-l

3-dioxolane (PMDO) as an electron donor can spontaneously co-polymerized with maleic anhydride (Manh)

methyl methacrylate (MMA) and acrylonitrile (AN) as the electron acceptors. The order of their polymerization activity and alternating-copolymerization tendency are: Manh>AN>MMA

which are the same as decreasing order of e values of the monomers. The formation of CT complexes PMDO-Manh and PMDO-AN was ascertained by UV and NMR spectroscopies. It was also discussed that the different protons of the same electron acceptor in the CT complexes have different chemical shifts.

关键词

自动共聚反应CT 络合物2-亚甲基-4-苯基-13-二氧环戊烷

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