纸质出版日期:1995-10-20
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讨论了超高分子量聚乙烯(UHMW-PE)的熔融一次拉伸和二次拉伸的晶体结构和力学性能.利用WAXD和SAXD测定了拉伸片的晶体取向因子和极图,晶粒尺寸,晶体畸变,长周期等晶体结构.用DSC和VES测定热性能和动态力学性能.应力-应变实验测定拉伸片的杨氏模量,断裂强度和伸长.这些实验结果说明UHMW-PE经二次拉伸能产生正交晶系的伸直链晶体.二次拉伸片由折叠链片晶和伸直链晶体两元结构组成.二次拉伸片的杨氏模量比一次拉伸片有大幅度提高.二次拉伸片的晶体结构和力学性能是在一次拉伸的基础上形成的.
The paper discussed the changes of crystal structure and mechanical properties of hot drawn and twice drawn sheets of UHMW-PE in melted state.The crvstal orientation of the drawn sheets were tested by using WAXD,the 200 and 020 pole figers were made and the orientation factors fa,fb and,fc were calcu-lated.The crystallite and amorphous region size along draw direction were obtain-ded by measuring the integral breadth of the 002 reflection profile and long period for the drawn sheets.The DSC curves for twice drawn UHMW-PE sheets showed that besides a main peak,a small melt peak was observed at 152--153℃.The dy-namic mechanical behavious for the hot drawn sheets and twice drawn sheets indica-ted that β-relaxation appears in lower draw ratio sheets and in higher draw ratio and twice drawn sheets β-relaxation degenerated greatly or disappeared.The Young’s modulus of twice drawn UHMW-PE were much higher than the first drawn one.The results showed that twice drawn UHMW-PE sheets had bi-component crystlliza-tion:most crystals were folded chain type,a few were extended chain crystals.Structures and properties of twice drawn sheets were improvement of first drawn one.
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