ZUO Ju, QIAO Feng-jun, Qian Ting-bao, MI Jiang-lin. THE CHARACTERIZATION OF INHOMOGENEITY OF SPATIAL DISTRIBUTION OF POLYMER NETWORK[J]. Acta Polymerica Sinica, 1995,(5):542-547.
ZUO Ju, QIAO Feng-jun, Qian Ting-bao, MI Jiang-lin. THE CHARACTERIZATION OF INHOMOGENEITY OF SPATIAL DISTRIBUTION OF POLYMER NETWORK[J]. Acta Polymerica Sinica, 1995,(5):542-547.DOI:
ased on the probing technique of laser light scattering and the principle of the determination for the inhomogeneity of spatial distribution of polymer network by means of non-random index NRI(=(Rvv(0))nr/(Rvv(0))r -1)
the inhomogeneity of a important functional cross-linking polymer
which is the copolymer of styrene with divinylbenzene
has been characterized successfully.Here subscripts nr
r denote nonrandom
random cross-linking network
respectively.And the former is from the experiments
the latter is from calculation. Futhermore
both have to be done in equilibrium swelling condition. Rvv(0) represents the Rayleigh ratio at zero angle under vertical both polarizer and analyser. The samller the NRI
the better the mechanical properties. As a result
a low NRI could be as a criterion for superior mechanical performance of frame of functional cross-linking copolymer.