磁场对聚乙烯基萘敏化AIBN引发苯乙烯本体光聚合反应的影响

黄骏廉; 朱平

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磁场对聚乙烯基萘敏化AIBN引发苯乙烯本体光聚合反应的影响

研究简报 | 更新时间：2021-03-19

- 磁场对聚乙烯基萘敏化AIBN引发苯乙烯本体光聚合反应的影响
- THE EFFECT OF MAGNETIC FIELD ON BULK PHOTO-POLYMERIZATION OF STYRENE INITIATED BY AIBN AND SENSITIZED BY PVN
- 高分子学报 1989年第2期页码：247-250
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- 纸质出版日期：1989-4-20，
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黄骏廉, 朱平. 磁场对聚乙烯基萘敏化AIBN引发苯乙烯本体光聚合反应的影响[J]. 高分子学报, 1989,(2):247-250.

HUANG Jun-lian, ZHU Ping. THE EFFECT OF MAGNETIC FIELD ON BULK PHOTO-POLYMERIZATION OF STYRENE INITIATED BY AIBN AND SENSITIZED BY PVN[J]. Acta Polymerica Sinica, 1989,(2):247-250.
黄骏廉, 朱平. 磁场对聚乙烯基萘敏化AIBN引发苯乙烯本体光聚合反应的影响[J]. 高分子学报, 1989,(2):247-250. DOI：

HUANG Jun-lian, ZHU Ping. THE EFFECT OF MAGNETIC FIELD ON BULK PHOTO-POLYMERIZATION OF STYRENE INITIATED BY AIBN AND SENSITIZED BY PVN[J]. Acta Polymerica Sinica, 1989,(2):247-250. DOI：

摘要

Abstract

The bulk polymerization of styrene initiated by AIBN which was sensitized by PVN could

be effected by magnetic field under irradiation with 320 nm monochromic light. The molecular weight distribution of polystyrene is dependent on the concentration and molecular weight of PVN. It was confirmed by experiments that the critical molecular weight and concentration of PVN which effected on the polymerization are 1.7×103 and 1.62×10-3 mol/l respectively. The cause which is responsible for these phenomena was discussed qualitatively.

关键词

外磁场聚乙烯基萘紫外光苯乙烯偶氮二异丁腈笼子效应

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