
浏览全部资源
扫码关注微信
纸质出版日期:1964-4-20,
扫 描 看 全 文
漆宗能, 魏楠仪. 环氧树脂的动态力学性能[J]. 高分子学报, 1964,6(2):103-107.
CHI TSUNG-NAN, WEI NAN-YI. DYNAMIC MECHANICAL PROPERTIES OF EPOXY RESINS[J]. Acta Polymerica Sinica, 1964,6(2):103-107.
用声频共振法在25—250℃温度范围内研究了以顺丁烯二酸酐固化的环氧树脂的动态力学性能。杨氏模量及内耗温度谱的实验结果指出:环氧树脂具有典型微少交联高聚物的力学性貭。随着固化程度的不同
大约在150℃左右已固化的环氧树脂由玻璃态转变为高弹态
此时模量急骤下降同时出现内耗峯
在此温度以上试样显示出橡皮高强特征。上述结果与其他一些研究结果一致
然而由内耗峯所确定的玻璃化转变温度却远高于及其同工作者用温度-形变曲綫法所测得的玻璃化转变温度。根据外力对动态力学性能的影响及我们以前的工作
我们认为外力有可能在环氧树脂分子网中产生了某种力化学效应
而动态力学结果与温度形变结果之间的差异可能正是由于此一原因。 根据实验结果还给出了以顺丁烯二酸酐固化的环氧树脂玻璃化转变温度与交联度间的关系
并对结果进行了讨论。
The dynamic mechanical properties of epoxy resins cured with maleic anhydride have been studied over the 25—250℃ temperature region using a vibrating reed method.The temperature dependence of Young’S modulus and the internal fric-tion for the cured epoxy resin is typical for a slightly crosslinked polymer. A pronounced dispersion rigion is noted near 150℃ (which varies with the degree of cure),and is accompained by a prominent drop in Young’S modulus in this region.The loss peak is due to the glass transition in the epoxy resin network since above this temperature the specimens exhibit a rubberlike behaviour. Results presented here agree well with those of other investigators.However.the glass transition temperature deter-mined bv internal friction peak is much higher than that determined from the thermo-mechanical curves by Kargin et al.,this difference suggests that the external force applied during a thermo-mechanical curve determination may produce certain mechano-chemical effects in the epoxy resin network.Experimental data obtained on the relation between the degree of crosslinking and the glass transition temperature are given and discussed.
0
浏览量
7
下载量
0
CSCD
关联资源
相关文章
相关作者
相关机构
京公网安备11010802024621