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纸质出版日期:1965-12-20,
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路之康, 葛增蓓, 田遇霖, 殷铭钧. 甲基丙烯酸十六酯溶液聚合[J]. 高分子学报, 1965,7(6):396-402.
LU CHIH-KANG, KE TZENG-PEI, Tien Yu-lin, YIN MING-CHUN. SOLUTION POLYMERIZATION OF CETYL METHACRYLATE[J]. Acta Polymerica Sinica, 1965,7(6):396-402.
甲基丙烯酸十六酯在有机溶剂中聚合时
溶剂结构对聚合速度没有显著影响。聚合体的平均分子量主要是受溶剂的链转移常数控制的
但在聚合过程中当生成的高聚物分子具有近似平均分子量时
由于高聚物分子在不同溶剂中具有不同的分子形态所产生的不同程度的粘度效应
对高转化率聚合体的平均分子量产生影响;同时
在高转化率聚合过程中聚合体平均分子量的均匀性与高聚物分子在溶剂中的形态有关
而与由聚合物的不同平均分子量在溶剂中所表现的不同粘度无关。
In order to find polymerization conditions for polycetyl methacrylate with homo-geneous molecular weight in higher conversion,we have studied the solution polymeriza-tion of cetyl methacrylate in carbon tetrachloride,chloroform,benzene,and sym-tetra-chloroethane.From the experimental data,the following conclusions can be drawn:(1)the chain transfer constants of the solvents selected above are lower than those jn the polymeriza-tion of methyl methacrylate under similar conditions;(2)the solution polymerization rates of cetyl methacrylate in the four given solvents are nearly the same;(3)in higher con-versions,the molecular weights of polycetylmethacrylate depend mainly on the chain transfer constants of the solvents,but under certain conditions the viscosity effect induced by polymeric molecular shape in the solvents might have some influence on the molecular weights of the polymer obtained;(4) homogeneity of the molecular weight of the poly-met is related probably to the polymeric molecular shape in the solvents,but not to the apparent viscosity of the solution.
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