FENG Han-bao, ZHOU Xiang-feng, Liang Wen-zhong, Lu Qi-hao, ZHAO Rui-nian. STUDIES ON THE COPOLYMERIZATION OF 2,2,6,6-TETRAME-THYL-4-PIPERIDINYL-ACRYLATES(III)[J]. Acta Polymerica Sinica, 1982,(2):126-129.
FENG Han-bao, ZHOU Xiang-feng, Liang Wen-zhong, Lu Qi-hao, ZHAO Rui-nian. STUDIES ON THE COPOLYMERIZATION OF 2,2,6,6-TETRAME-THYL-4-PIPERIDINYL-ACRYLATES(III)[J]. Acta Polymerica Sinica, 1982,(2):126-129.DOI:
The copolymerization of MTMP(2,2,6,6-tetramethyl-4-piperidinylmethacrylate,M1) with St(styrene,M2),MVK(Methylvinylketone,M2),AN(acrylonitrile,2)and VAe (vinyl acetate,M2) was conducted in benzene at 60±0.1℃ by using ABVN (or AIBN) as initiator.The composition curves of the eopolymers and the monomer reac-tivity ratios of four pairs of monomers have been determined(MTMP.St:γ1=0.30士0.05,γ2=0.63±0.05;MTMP-MVK;γ1=0.53土0.05,γ2=0.41±0.05;MTMP.VAc:γ1=14土0.5,γ2=0.02±0.01;MTMP—AN:γ1=13.7±0.5,γ2=0.20士0.05).The Q(0.56) and e(0.49)values of MTMP have been calculated and the microstructure of the copolymer has been described.