Zhou Xing-mao, Zhou En-lo, Liu Ren-ru. EFFECT OF SUPERMOLECULAR STRUCTURE OF POLYETHYLENE ON IRRADIATION CROSS-LINKING[J]. Acta Polymerica Sinica, 1982,(2):103-108.
Zhou Xing-mao, Zhou En-lo, Liu Ren-ru. EFFECT OF SUPERMOLECULAR STRUCTURE OF POLYETHYLENE ON IRRADIATION CROSS-LINKING[J]. Acta Polymerica Sinica, 1982,(2):103-108.DOI:
The morphological structure of PE obviously affects irradiated crosslinking. The more irregular in the arrangement of the structure of crystalline morphology is
the lower in crystallity and more interface will be
resulting in the formation of more crosslinkis between molecules.Through observation of spherulite deformation by drawing
etching and melting
We may perceive that crosslinking can occur at all interfaces
preferentially between lamellas.When the amount of gel reaches 92%
with the incresing of the does of irradia-tion the crystallinety decreases and the size of crystal becomes smaller. At the same time
the refractive index and density increase while the segmental orientation of macromolecule decreases.