用苯乙烯和4-(甲基丙烯酸)2,2,6,6-四甲基哌啶醇酯共聚物共混改性聚丙烯纤维的研究

吕起镐; 郑国秀; 梁文忠; 冯汉保; 孙若讷; 后晓淮; 周祥风; 苏炳录; 赵瑞年; 沈德康

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用苯乙烯和4-(甲基丙烯酸)2,2,6,6-四甲基哌啶醇酯共聚物共混改性聚丙烯纤维的研究

研究论文 | 更新时间：2021-03-19

- 用苯乙烯和4-(甲基丙烯酸)2,2,6,6-四甲基哌啶醇酯共聚物共混改性聚丙烯纤维的研究
- STUDIES ON MODIFIED POLYPROPYLENE FIBERS, PROPERTIES OF FIBER SPUN FROM A POLYBLEND OF POLYPROPYLENE AND A COPOLYMER OF STYRENE AND 2, 2, 6, 6-TETRA-METHYL-4-PIPERIDINYLMETHACRYLATE
- 高分子学报 1979年第5期页码：285-290
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- 纸质出版日期：1979-10-20，
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吕起镐, 郑国秀, 梁文忠, 冯汉保, 孙若讷, 后晓淮, 周祥风, 苏炳录, 赵瑞年, 沈德康. 用苯乙烯和4-(甲基丙烯酸)2,2,6,6-四甲基哌啶醇酯共聚物共混改性聚丙烯纤维的研究[J]. 高分子学报, 1979,(5):285-290.

Lu Qi-hao, Zheng Guo-xiu, Liang Wen-zhong, FENG Han-bao, Sun Euo-na, Hou Xiao-huai, Zhou Xiang-feng, Su Bing-lu, ZHAO Rui-nian, Shen De-kang. STUDIES ON MODIFIED POLYPROPYLENE FIBERS, PROPERTIES OF FIBER SPUN FROM A POLYBLEND OF POLYPROPYLENE AND A COPOLYMER OF STYRENE AND 2, 2, 6, 6-TETRA-METHYL-4-PIPERIDINYLMETHACRYLATE[J]. Acta Polymerica Sinica, 1979,(5):285-290.
吕起镐, 郑国秀, 梁文忠, 冯汉保, 孙若讷, 后晓淮, 周祥风, 苏炳录, 赵瑞年, 沈德康. 用苯乙烯和4-(甲基丙烯酸)2,2,6,6-四甲基哌啶醇酯共聚物共混改性聚丙烯纤维的研究[J]. 高分子学报, 1979,(5):285-290. DOI：

Lu Qi-hao, Zheng Guo-xiu, Liang Wen-zhong, FENG Han-bao, Sun Euo-na, Hou Xiao-huai, Zhou Xiang-feng, Su Bing-lu, ZHAO Rui-nian, Shen De-kang. STUDIES ON MODIFIED POLYPROPYLENE FIBERS, PROPERTIES OF FIBER SPUN FROM A POLYBLEND OF POLYPROPYLENE AND A COPOLYMER OF STYRENE AND 2, 2, 6, 6-TETRA-METHYL-4-PIPERIDINYLMETHACRYLATE[J]. Acta Polymerica Sinica, 1979,(5):285-290. DOI：

摘要

用苯乙烯和4-(甲基丙烯酸)-2

6-四甲基哌啶醇酯共聚物与聚丙烯共混

进行纺丝

得到了一种洁白的消光纤维

纺丝温度显著降低

纤维的抗大气老化性能好

并可用偶氮型分散染料染色

改进了聚丙烯纤维的一些缺点。

Abstract

6-Tetramethyl-4-piperidinylmethacrylate was prepared by ester-exchange reaction between 2

6-tetramethyl-4-piperidinol and methylmethacrylate. The resulting ester was copolymerized with styrene

and the copolymer was blended with polypropylene in quantities of 1.5-5%. The polyblends thus obtained were spun into fibers with a tenacity of about 4g/d. The modified fibers have a good resistance to weathering

and good dyeing ability with azo-type dispersive dyes. At the same time the spinning temperature of the polyblends was lowered to around 280℃.

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