ZHANG Rong-ben, BEI Jian-zhong, CHEN Bu-shi, YE Li-mei. SYNTHESIS OF METHYLSILANOL-TERMINATED SILICONE RESINS AND THEIR THERMOSETTING PROPERTIES[J]. Acta Polymerica Sinica, 1985,(5):325-330.
ZHANG Rong-ben, BEI Jian-zhong, CHEN Bu-shi, YE Li-mei. SYNTHESIS OF METHYLSILANOL-TERMINATED SILICONE RESINS AND THEIR THERMOSETTING PROPERTIES[J]. Acta Polymerica Sinica, 1985,(5):325-330.DOI:
1,1,5,5-tetrachloro-1,5-dimethyl-3,3-diphenyltrisiloxane (A) and 1,1,5,5-tetrame-thyl-1,5-dichloro-3,3-diphenyltrisiloxane (B) Were obtained by the reactions of methylt-richlorosilane and dimethyldichlorosilane with diphenyldichlorosilane,respectively.The wholly methylsilanol-terminated silicone resin (I) was prepared from (A) and (B) in proper pzoportion.Also.two another kinds of methylsilanol-terminated silicone resins (II) and (III) were produced by the reactions of methyltrichIorosilane and methyltria-cetoxyisilane
respectively
with the phenylsilanolterminated silicone resins prepared by the hsual cohydrolysis method.The methylsilanol-terminated silicoffe resins(I,II,III) can be cured more than two times faster than the phenylsilanol-terminated silicone resins prepared by the usual cohydrolysis method.