DONG Yanming, CHENG Zhifeng. STUDIES ON THE ORIENTED AND UNORIENTED FILMS OF A LIQUID CRYSTALLINE WHOLLY AROMATIC COPOLYESTER USIING TECHNIQUE OF BANDED TEXTURE DECORATION[J]. Acta Polymerica Sinica, 1996,(5):591-595.
DONG Yanming, CHENG Zhifeng. STUDIES ON THE ORIENTED AND UNORIENTED FILMS OF A LIQUID CRYSTALLINE WHOLLY AROMATIC COPOLYESTER USIING TECHNIQUE OF BANDED TEXTURE DECORATION[J]. Acta Polymerica Sinica, 1996,(5):591-595.DOI:
Banded texture was decorated on oriented films of 4-hydroxybenzoic acid-2-hydroxy-6-naphthoic acid copolymer by annealing.The fibrils of three levels
Which were macrofibrils of several tens micron in diameter
fibrils feW micron and microfibrils about 0.3 micron
were observed simultaneously with banded texture usingpolarized microscope.After annealing
fibrils in different levels relaxed to differentmorphology.Macrofibrils still oriented along shear direction
but fibrils relaxed to helical form
and microfibrils relaxed to waveform therefore the banded texture canbe seen.The smaller the diameter of fibrils was
the more easily the fibrils relaxed.Ori the other hand
the banded texture decoration of annealed unoriented filmsrevealed directly the distribution of directors within and out of domains and thevariation of directors on boundaries.The formation of banded texture iS explained byslow effect of constricting elastic force of macromoleeules on relaxation duringannealing.