CHEN Yuan-yin, LU Xue-ran, CAI Ming-zhong. SYNTHESIS AND CATALYTIC CHARACTERISTICS OF POL YSILOXANE-SUPPORTED THIIRANE PLATINUM COMPLEX[J]. Acta Polymerica Sinica, 1990,(4):489-491.
CHEN Yuan-yin, LU Xue-ran, CAI Ming-zhong. SYNTHESIS AND CATALYTIC CHARACTERISTICS OF POL YSILOXANE-SUPPORTED THIIRANE PLATINUM COMPLEX[J]. Acta Polymerica Sinica, 1990,(4):489-491.DOI:
7-epithioheptylsiloxane platinum complex was synthesized from γ-(2
3-epithiopropoxy) propyltrimethoxysilane via immobilization on fumed silica
followed by reacting with potassium chloroplatinite in acetone. It was found that the title complex exhibits high catalytic activity for the hydrosilylation of olefins by triethoxysilane and excellent recovery and reuse properties. The yield of decyltriethoxysilane was unchanged from the second run to fifteenth run.