YAN Weng-e, CHEN Jie, LU Li-zhen, WANG Shi-cai. THE STRUCTURE AND PROPERTIES OF PLASMA POLY MERIZED VINYLTRIMETHYLSILANE[J]. Acta Polymerica Sinica, 1990,(1):36-44.
YAN Weng-e, CHEN Jie, LU Li-zhen, WANG Shi-cai. THE STRUCTURE AND PROPERTIES OF PLASMA POLY MERIZED VINYLTRIMETHYLSILANE[J]. Acta Polymerica Sinica, 1990,(1):36-44.DOI:
In a capacitively coupled discharge witih external electrodes
vinyltrimethylsilane (VTMS) was polymerized. The polymer structure was characterized with IR
XPS
PGC/MS
X-ray
ESR and elemental analysis. A polymerization mechanism was speculated. The thermal property of the polymer was studied by means of TG analysis. The polymer is found to be amorphous through X-ray study. XPS examination indicates that oxygen is incorporated into the polymer chain when plasma gases are not added
and the C/Si ratios of poly-mer are lower than that of polymer in general. TG study indicates that the polymer has better thermal stability.