LIN Si-cong, CHEN Jing-ping, GUAN Jian-ning, WU Jing-di, LU Yun. STUDIES ON p-CHLOROMETHYL STYRENE AND ITS HOMOPOLYMER[J]. Acta Polymerica Sinica, 1991,(2):238-242.
LIN Si-cong, CHEN Jing-ping, GUAN Jian-ning, WU Jing-di, LU Yun. STUDIES ON p-CHLOROMETHYL STYRENE AND ITS HOMOPOLYMER[J]. Acta Polymerica Sinica, 1991,(2):238-242.DOI:
p-Chloromethyl styrene (p-CMS) is a new industrial monomer and is attractive for both science and industry. In this paper
many important physicochemical data including IR
UV
1H-NMR
13C-NMR
MS of the monomer and TGA
solubility parameter of the polymer are shown. On the basis of explored kinetic results
the equation Rp= K[AIBN]0.5[ p-CMS]1.5 is proposed to express the initial overall rate of the polymerization of p-CMS in the presence of AIBN as an initiator. In the light of the results from TGA
an inference that the thermodegra-dation seems to be the main reaction during the thermal decomposition of poly-p-CMS in nitro-gen is given.