丙烯酸甲酯与N-对卤苯基甲基丙烯酰胺共聚合的研究

丁有骏; 齐大荃; 吕木坚; 叶东浩

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丙烯酸甲酯与N-对卤苯基甲基丙烯酰胺共聚合的研究

研究简报 | 更新时间：2021-03-19

- 丙烯酸甲酯与N-对卤苯基甲基丙烯酰胺共聚合的研究
- COPOLYMERIZATION OF METHYL-ACRYLATE(MA) AND N-p-HALOPHENYLMETHACRYLAMIDE (N-p-XPhMA)
- 高分子学报 1990年第5期页码：632-636
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- 纸质出版日期：1990-10-20，
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丁有骏, 齐大荃, 吕木坚, 叶东浩. 丙烯酸甲酯与N-对卤苯基甲基丙烯酰胺共聚合的研究[J]. 高分子学报, 1990,(5):632-636.

DING You-jun, QI Da-quan, LU Mu-jian, YE Tong-hao. COPOLYMERIZATION OF METHYL-ACRYLATE(MA) AND N-p-HALOPHENYLMETHACRYLAMIDE (N-p-XPhMA)[J]. Acta Polymerica Sinica, 1990,(5):632-636.
丁有骏, 齐大荃, 吕木坚, 叶东浩. 丙烯酸甲酯与N-对卤苯基甲基丙烯酰胺共聚合的研究[J]. 高分子学报, 1990,(5):632-636. DOI：

DING You-jun, QI Da-quan, LU Mu-jian, YE Tong-hao. COPOLYMERIZATION OF METHYL-ACRYLATE(MA) AND N-p-HALOPHENYLMETHACRYLAMIDE (N-p-XPhMA)[J]. Acta Polymerica Sinica, 1990,(5):632-636. DOI：

摘要

Abstract

The MA-co-N-p-BrPhMA(Methyl-acrylate-co-N-p-Bromophenylmethacrylamide) and MA-co-N-p-ClPhMA (Methyl-acrylate-co-N-p-Chloro-phenylmethacrylamide) bulk copolymers were prepared and characterized by I. R. and 1H-NMR method.The compositions of the copolymers were determined from the areas of the phenyl group and methoxy group proton peaks in the proton NMR spectra.Reactivity ratios were calculated from the composition data by the Fineman-Ross method; the following values were obtained:r1= 1.33±0.02(MA)

r2= 0.42±0.02(N-p-BrPhMA) for MA-co=N-p-BrPhMA copolymer.

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