二烷基锡聚合物的研究——Ⅲ.顺丁烯二酸二丁基锡酯与丙烯酸甲酯、丙烯酸丁酯的共聚合

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- 二烷基锡聚合物的研究——Ⅲ.顺丁烯二酸二丁基锡酯与丙烯酸甲酯、丙烯酸丁酯的共聚合
- STUDIES ON THE DIALKYLTIN POLYMERS III. COPOLYMERIZATION OF DIBUTYLTIN MALEATE WITH METHYL ACRYLATE AND BUTYL ACRYLATE
- 高分子学报 1991年第5期页码：625-630
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- 纸质出版日期：1991-10-20，
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吴元辉, 杨梅英, 陈鸿熙. 二烷基锡聚合物的研究——Ⅲ.顺丁烯二酸二丁基锡酯与丙烯酸甲酯、丙烯酸丁酯的共聚合[J]. 高分子学报, 1991,(5):625-630.

WU Yuan-hui, YANG Mei-ying, CHEN Hong-xi. STUDIES ON THE DIALKYLTIN POLYMERS III. COPOLYMERIZATION OF DIBUTYLTIN MALEATE WITH METHYL ACRYLATE AND BUTYL ACRYLATE[J]. Acta Polymerica Sinica, 1991,(5):625-630.
吴元辉, 杨梅英, 陈鸿熙. 二烷基锡聚合物的研究——Ⅲ.顺丁烯二酸二丁基锡酯与丙烯酸甲酯、丙烯酸丁酯的共聚合[J]. 高分子学报, 1991,(5):625-630. DOI：

WU Yuan-hui, YANG Mei-ying, CHEN Hong-xi. STUDIES ON THE DIALKYLTIN POLYMERS III. COPOLYMERIZATION OF DIBUTYLTIN MALEATE WITH METHYL ACRYLATE AND BUTYL ACRYLATE[J]. Acta Polymerica Sinica, 1991,(5):625-630. DOI：

Benzoyl peroxide (BPO) was used for initiator in copolymerization of dibutyltin maleate (DBTM

M2) with methyl acrylate (MA

M1) in benzene and the reactivity ratios of copolymerization r1 and r2 were found to be 12.67 and 0.03

respectively. But in copolymerization of DBTM (M2) with butyl acrylate (BA

M1) r1 and r2 were 11.1 and 0> respectively. The cc-polymerization conditions

such as amount of initiator

ratios of monomers and addition method of initiator were examined. Copolymers were characterized by 1H-NMR

elemental and TG analyses. MA-DBTM copolymer is a white and brittle solid

while BA-DBTM copolymer is a transparent elastomer at room temperature.

丁烯二酸二丁基锡酯有机锡共聚物竞聚率1H-NMRIR

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