STRUCTURE AND MECHANICAL PROPERTY STUDIES ON THE SUPERDRAWN FILMS OF ULTRAHIGH MOLECULAR WEIGHT POLYPROPYLENE I. CHARACTERIZATION OF THE DRAWING/ORIENTATION PROCESSING
WU Gang, JIANG Jiao-dong, SUN Quan-song. STRUCTURE AND MECHANICAL PROPERTY STUDIES ON THE SUPERDRAWN FILMS OF ULTRAHIGH MOLECULAR WEIGHT POLYPROPYLENE I. CHARACTERIZATION OF THE DRAWING/ORIENTATION PROCESSING[J]. Acta Polymerica Sinica, 1992,(2):148-156.
WU Gang, JIANG Jiao-dong, SUN Quan-song. STRUCTURE AND MECHANICAL PROPERTY STUDIES ON THE SUPERDRAWN FILMS OF ULTRAHIGH MOLECULAR WEIGHT POLYPROPYLENE I. CHARACTERIZATION OF THE DRAWING/ORIENTATION PROCESSING[J]. Acta Polymerica Sinica, 1992,(2):148-156.DOI:
A superdrawn technique called crystal real drawing has beea applied to obtain the oriented isotactic polypropyIene (i-PP) films.Orystal mat of ultrahigh moIecular weight i-PP(Mw-4×106) obtained by crystallization from its dilute xylene solution,exhibits a dramatlcally high de-formability compared to both the low toolecular weight mat and the mek-crystallized forms.such cryatsl mats are prepared to a series of samples with the various draw ratios and the highest draw ratio can be achieved up to 69.An X-ray diffraction photograph shows that the c-axis of the lamellar crystals in the original mat orient preferentially in the normal direction of the mat plane,and such crystals had already been split and c-axis orientation had been turned to parallel with the draw direction in the draw ratio range of 110 and D040 decrease as the draw ratio is in-creased,but the long period L found to becomelarger with the draw ratio raise up to the high value.These results indicate that lamellar crystals are deformed through a chain folds unrave-ling and then partially recrganized into a fully straight crystalline structure.