QIU Kun-yuan, YE Ke-qiang. POLYMERIZATION AND COPOLYMERIZATION OF N-(PARA-METHYLPHENYL) MALEIMIDE INITIATED BY N,N- DIMETHYL-PARA-TOLUIDINE UNDER UV LIGHT IRRADIATION[J]. Acta Polymerica Sinica, 1993,(1):125-128.
QIU Kun-yuan, YE Ke-qiang. POLYMERIZATION AND COPOLYMERIZATION OF N-(PARA-METHYLPHENYL) MALEIMIDE INITIATED BY N,N- DIMETHYL-PARA-TOLUIDINE UNDER UV LIGHT IRRADIATION[J]. Acta Polymerica Sinica, 1993,(1):125-128.DOI:
N-(p-methylphenyl) maleimide (PMPMI) was synthesized from the reaction of maleic anhydride with p-methylaniline via two steps processes. Radical polymerization of PMPMI using AIBN as an initiator or initiated with N
N-dimethyl-p-toluidine (DMT) under UV light irradiation have been investigated. Copolymerizations of methyl acrylate (MA)
methyl me-thacrylate (MMA) with PMPMI were carried out in THF and cyclohexanone respectively. It was found that the molecular weights of the polymers and copolymers obtained from the cyclo hexanone were always greater than that of from THF. The monomer reactivity ratios were cal-culated.