HU Jiacong, CHEN Shaohua, SHAO Nianci. STUDIES ON THE CRYSTALLINITY,ORIENTATION AND SUPERSTRUCTURE OF HARD ELASTIC POLYPROPYLENE BY FRS XRSA AND SAXS Ⅲ. THE STRETCHING AND RECOVERY[J]. Acta Polymerica Sinica, 1997,(1):1-7.
HU Jiacong, CHEN Shaohua, SHAO Nianci. STUDIES ON THE CRYSTALLINITY,ORIENTATION AND SUPERSTRUCTURE OF HARD ELASTIC POLYPROPYLENE BY FRS XRSA AND SAXS Ⅲ. THE STRETCHING AND RECOVERY[J]. Acta Polymerica Sinica, 1997,(1):1-7.DOI:
The work is to investigate the effect of the stretching and recovery processes on the microstructure
orientation texture and superstructure of hard elastic polypropylene (HEPP) fibers by FRS XRSA and SAXS.The results show that strain induced crystallization
but when ε ≥30%
X W C approaches a conatant
~90%;strain induced the fragmentation of crystallites;strain induced the lamellae separation in parallel
not induced leaf spring bending
i.e.as ε increases
the orientation distribution of crystallites does not change;when ε≤30%
the lamellae separation is the main process
when ε>30%
the lamellae layers occur fracture and slip along the fiber-axis
thus
before and after ε=30% the atrain mechaniem of the hard elaticity is different;strain-induced microvoids in HEPP
but as ε≥20%
the microvoids'size approaches a definite value.These results have successfully been used to interpret the relationships between the structure and properties of HEPP.