ZHUO Renxi, ZHANG Xianzheng. STUDIES ON THE SYNTHESIS AND CHARACTERIZATION OF TEMPERATURE AND pH SENSITIVE POLY(ACRYLIC ACID) co (ACRYLONITRILE) HYDROGELS[J]. Acta Polymerica Sinica, 1997,(4):500-503.
ZHUO Renxi, ZHANG Xianzheng. STUDIES ON THE SYNTHESIS AND CHARACTERIZATION OF TEMPERATURE AND pH SENSITIVE POLY(ACRYLIC ACID) co (ACRYLONITRILE) HYDROGELS[J]. Acta Polymerica Sinica, 1997,(4):500-503.DOI:
A lot of polymeric hydrogels undergo volume changes in response to external stimuli such as pH
temperature
electric field and light.These intelligent hydrogels have been used for the preparation of a wide variety of devices
for instance
immobilized enzyme
recyclable absorbents and controlled drug release.However
most of the hydrogels studied previously are responsive to only one kind of stimulus.But for some situations
responsiveness to several stimuli
such as temperature and pH
may be requied.We wish to report here the synthesis of a new intelligent hydrogel which can response to temperature and pH at the same time.Poly (acrylic acid_-co-(acrylonitrile) Hydrogels were synthesized.The Temperatura and pH sensitivities of these hydrogels were studied.The swelling ratio(SR) of hydrogels at various pH values is different.In water medium
SR of hydrogels at elevated temperature(62℃) is increased with the prolongation of time.However
this phenomenon is not so obvious in weak alkaline and acidic solutions.