CHEN Yi-yong, YUAN Xing-zhong, JI Ming-rong, XU Wen-ying. SYNTHESIS OF 1-(2-AMINOETHYL) PYRROLIDINE RESIN AND ITS SORPTION FOR NOBLE METAL IONS[J]. Acta Polymerica Sinica, 1993,(2):225-232.
CHEN Yi-yong, YUAN Xing-zhong, JI Ming-rong, XU Wen-ying. SYNTHESIS OF 1-(2-AMINOETHYL) PYRROLIDINE RESIN AND ITS SORPTION FOR NOBLE METAL IONS[J]. Acta Polymerica Sinica, 1993,(2):225-232.DOI:
and reaction time on the synthesis of 1-(2-aminoethyl) pyrrolidine resin (AEPDR) have been studied. The functional group capacity of AEPDR is 2.74 mmol/g resin. The sorption capacities of AEPDR for Au (III)
Os(IV)
Pt(IV)
Ir(IV)
Ru(III)
and Pd(II) are as high as 950
520
436
418
314
and 302 mg ion/g resin
respectively. The structure of AEPDR was confirmed by FT-IR and elementary analysis. The sorption rate curves and complex ratio were determined. The apparent sorption activation energies for Au(III) and Pt(IV) are △EAu=6.3 and △EPt=33.7 kJ/mol
respectively. The sorption mechanism has been nvestigated by XPS.