N-甲基丙烯酰-N′-嘧啶基哌嗪及其聚合物的荧光光谱研究

高青雨; 张举贤; 李福绵

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N-甲基丙烯酰-N′-嘧啶基哌嗪及其聚合物的荧光光谱研究

研究简报 | 更新时间：2021-03-19

- N-甲基丙烯酰-N′-嘧啶基哌嗪及其聚合物的荧光光谱研究
- A FLUORESCENCE STUDY FOR N-METHACRYLYL-N'- PYRIMIDINOPIPERAZINE AND ITS POLYMER
- 高分子学报 1992年第6期页码：726-731
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- 纸质出版日期：1992-12-20，
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高青雨, 张举贤, 李福绵. N-甲基丙烯酰-N′-嘧啶基哌嗪及其聚合物的荧光光谱研究[J]. 高分子学报, 1992,(6):726-731.

GAO Qing-yu, ZHANG Ju-xian, LI Fu-mian. A FLUORESCENCE STUDY FOR N-METHACRYLYL-N'- PYRIMIDINOPIPERAZINE AND ITS POLYMER[J]. Acta Polymerica Sinica, 1992,(6):726-731.
高青雨, 张举贤, 李福绵. N-甲基丙烯酰-N′-嘧啶基哌嗪及其聚合物的荧光光谱研究[J]. 高分子学报, 1992,(6):726-731. DOI：

GAO Qing-yu, ZHANG Ju-xian, LI Fu-mian. A FLUORESCENCE STUDY FOR N-METHACRYLYL-N'- PYRIMIDINOPIPERAZINE AND ITS POLYMER[J]. Acta Polymerica Sinica, 1992,(6):726-731. DOI：

摘要

Abstract

A novel acrylic monomer bearing pyrimidino-moiety

N-methacrylyl-N'-pyrimidinopipe-razine (MPMP) was synthesized by the reaction of N-pyrimidinopiperazine and methacrylyl chloride in the presence of triethylamine. Both absorption and fluorescence spectum for the monomer and its polymer were recorded. It was observed that the fluorescence intensity of monomeric MPMP was slightly lower than that of its polymer. The monomer did not dramatically appear its structural self-quenching effect as we have reported previously. The fluores-cence of the polymer

P(MPMP) culd be quenched by electron-deficient quenchers such as methacrylonitrile

acrylonitrile

fumaronitrile; methyl acrylate and methyl methacrylate. The Stern-Volmer constants of those quenchers for P(MPMP) were determined.

关键词

N-甲基丙烯酰-N’-嘧啶哌嗪含胺基功能性单体结构自猝灭现象荧光光谱激基复合物e-值Stern-Volmer常数

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