ZHANG Sheng-shui, WAN Guo-xiang. LITHIUM-IONIC CONDUCTION IN THE BLEND OF THE COMB-LIKE POLYETHER WITH LITHIUM POLYSULFONATE[J]. Acta Polymerica Sinica, 1993,(1):42-46.
ZHANG Sheng-shui, WAN Guo-xiang. LITHIUM-IONIC CONDUCTION IN THE BLEND OF THE COMB-LIKE POLYETHER WITH LITHIUM POLYSULFONATE[J]. Acta Polymerica Sinica, 1993,(1):42-46.DOI:
Poly foligo(oxyethylene) methacrylate] and poly(methacryloyl hexylsulfonic acid lithium) were successfully synthesized
from which the blends with single-Li+-ionic conduction were prepared. The Li+-ionic conductivity was deeply influenced by the compatibility
composition and temperature of the blends. The results show that the better the compatibility of the blends
the higher the conductivity. Li+Monic migration in the blend occurs mainly in amorphour regions and accelerates with increasing segmental motion of the matrix polymers. An optimum Li+-ionic conductivity of 5.3×10-7S/cm at 25℃ was observed for the homogeneous blend PMEO18/P(0.5SHMLi-0.5HEMA) with O/L:=70.