含胺基功能性单体的聚合研究——ⅩⅦ.N-(4-二甲氨基苯基)马来酰亚胺的聚合及其光化学行为

蔡辉; 李福绵

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含胺基功能性单体的聚合研究——ⅩⅦ.N-(4-二甲氨基苯基)马来酰亚胺的聚合及其光化学行为

研究简报 | 更新时间：2021-03-19

- 含胺基功能性单体的聚合研究——ⅩⅦ.N-(4-二甲氨基苯基)马来酰亚胺的聚合及其光化学行为
- STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO GROUP XVII. POLYMERIZATION AND PHOTOCHEMICAL BEHAVIOR OF N-(p-DIMETHYLAMINOPHENYL) MALEIMIDE
- 高分子学报 1993年第3期页码：370-374
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- 纸质出版日期：1993-6-20，
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蔡辉, 李福绵. 含胺基功能性单体的聚合研究——ⅩⅦ.N-(4-二甲氨基苯基)马来酰亚胺的聚合及其光化学行为[J]. 高分子学报, 1993,(3):370-374.

CAI Hui, LI Fu-mian. STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO GROUP XVII. POLYMERIZATION AND PHOTOCHEMICAL BEHAVIOR OF N-(p-DIMETHYLAMINOPHENYL) MALEIMIDE[J]. Acta Polymerica Sinica, 1993,(3):370-374.
蔡辉, 李福绵. 含胺基功能性单体的聚合研究——ⅩⅦ.N-(4-二甲氨基苯基)马来酰亚胺的聚合及其光化学行为[J]. 高分子学报, 1993,(3):370-374. DOI：

CAI Hui, LI Fu-mian. STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO GROUP XVII. POLYMERIZATION AND PHOTOCHEMICAL BEHAVIOR OF N-(p-DIMETHYLAMINOPHENYL) MALEIMIDE[J]. Acta Polymerica Sinica, 1993,(3):370-374. DOI：

摘要

Abstract

N-(p-Dimethylaminophenyl)maleimide (DMAPMI) was synthesized and copolymerized with vinyl acetate. The photochemical behavior of DMAPMI and its polymer was studied. It was found that the intensity of monomer was lower than that of its copolymer due to the structural self-quenching effect as we have reported previously. The relationship between Stern-Volmer constant and 'e' value of quenchers was discussed. DMAPMI could act as both of a photosensitizer for vinyl polymerization upon UV irradiation and a component of redox initiation system by combining with BPO to initiate the vinyl thermo-polymerization.

关键词

N-（P-二甲氨基苯基）马来酰亚胺荧光发射光谱荧光结构自猝灭效应Stern-Volmer常数

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