N-甲基丙烯酰-N′-嘧啶基哌嗪及其聚合物敏化的丙烯腈光聚合

高青雨; 张举贤; 李福绵

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N-甲基丙烯酰-N′-嘧啶基哌嗪及其聚合物敏化的丙烯腈光聚合

研究简报 | 更新时间：2021-03-19

- N-甲基丙烯酰-N′-嘧啶基哌嗪及其聚合物敏化的丙烯腈光聚合
- PHOTOPOLYMERIZATION OF ACRYLONITRILE SENSITIZED BY N-METHACRYL YL-N'-PYRIMIDINOPIPERAZINE AND ITS POLYMER
- 高分子学报 1992年第5期页码：628-632
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- 纸质出版日期：1992-10-20，
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高青雨, 张举贤, 李福绵. N-甲基丙烯酰-N′-嘧啶基哌嗪及其聚合物敏化的丙烯腈光聚合[J]. 高分子学报, 1992,(5):628-632.

GAO Qing-yu, ZHANG Ju-xian, LI Fu-mian. PHOTOPOLYMERIZATION OF ACRYLONITRILE SENSITIZED BY N-METHACRYL YL-N'-PYRIMIDINOPIPERAZINE AND ITS POLYMER[J]. Acta Polymerica Sinica, 1992,(5):628-632.
高青雨, 张举贤, 李福绵. N-甲基丙烯酰-N′-嘧啶基哌嗪及其聚合物敏化的丙烯腈光聚合[J]. 高分子学报, 1992,(5):628-632. DOI：

GAO Qing-yu, ZHANG Ju-xian, LI Fu-mian. PHOTOPOLYMERIZATION OF ACRYLONITRILE SENSITIZED BY N-METHACRYL YL-N'-PYRIMIDINOPIPERAZINE AND ITS POLYMER[J]. Acta Polymerica Sinica, 1992,(5):628-632. DOI：

摘要

Abstract

The photopolymerization of acrylonitrile (AN) sensitized by N-methacrylyl-N'-pyrimidi-nopiperazine (MPMP) and its polymer

P(MPMP) was studied kinetically. It was found that the photopolymerization rate of AN sensitized by monomeric MPMP is proportional to 0.35th power of MPMP concentration and 0.85th power of AN concentration

respectively. In the case sensitized by Polymeric MPMP

P(MPMP) is proportional to 0.30th power of P(MP-MP) concentration and 1.0 power of AN concentration

respectively. The overall activation energies for photopolymerization sensitized with MPMP and P(MPMP) were determined to be 4.71Kcal/mol and 4.58Kcal/mol

respectively.From the fluorescence analysis for P(AN) senstitized by either MPMP or P(MPMP)

it was confirmed that MPMP and P(MPMP) not only sensitized the photopolymerization of AN but also entered into the P(AN) chains.

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N-甲基丙烯酰-N’-嘧啶哌嗪丙烯腈光聚合

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