采用静电纺丝技术,制备了聚醚砜(PES)纤维膜,探讨了其溶液浓度对所纺纤维微观形貌的影响,同时研究了纤维膜的面密度对过滤效率和压降的影响.为降低过滤压降,在纤维中加入微球,研究了纤维与微球复合方式对过滤性能的影响.复合纤维膜是以聚丙烯(PP)无纺布为支撑层,与所制纤维膜相比过滤效率和压降可忽略不计.实验结果表明,PES浓度为280 g/L时,所得纤维粗细均匀,平均直径为510 nm;PES浓度为200 g/L时,得到PES微球结构,微球直径2.74 m.当PES纤维膜的面密度由7.5 g/m2增至10.5 g/m2时,过滤压降则由706.58 Pa 升至1444.52 Pa,且过滤效率均可到达99.99%.这表明面密度对过滤压降的影响大于对过滤效率的影响.在两层纤维膜间加入微球,过滤压降、效率均会出现明显下降,但在纤维间引入适量微球,则会降低过滤压降,而纤维膜过滤效率不受影响,若微球量加入过多,反而会增加过滤压降.
Abstract
The objective of this study is to evaluate the effect of poly(ether sulfone) (PES) concentration on microstructure of the electrospun hanofifers and the effect of nanofiber layer density on filtration efficiency and pressure drop of filters with nanofibers coated on a substrate.In order to reduce the pressure drop
the influence of composite methods on the filter performance by adding a certain amount of microspheres into the fibers was studied.The substrate is a non-woven polypropylene (PP) medium with negligible filtration efficiency and pressure drop as compared to the nanofiber layer.Experimental results show that when PES concentration(W/V) is 280 g/L well-distributed nanofibers with mean diameter of 510 nm are formed
and when PES concentration is 200 g/L a structure of microspheres with mean diameter of 2.74 m is obtained.The pressure drop increases from 706.58 Pa to 1444.52 Pa when packing density increases from 7.5 g/m2 to 10.5 g/m2
while the filtration efficiency can generally reach to 99.99%.This suggests nanofiber packing density has less prominent effect on filtration efficiency than pressure drop.By adding microspheres between two layers of fibers
the pressure drop across the filter decreases but the filtration efficiency also decreases.For the microspheres/fiber composite membranes
an appropriate amount of microspheres in the fibers will reduce the pressure drop but the filtration efficiency is reduced little.However too much microspheres will increase the filter pressure drop.Hence
the method of adding microspheres into nanofiber is proposed to fabricate nanofiber filter with greatly reduced pressure drop.This is advantageous for high efficiency applications with nanofibers of low pressure drop.