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浙江理工大学 生态染整技术教育部工程研究中心 先进纺织材料与制备技术教育部重点实验室,杭州,310018
纸质出版日期:2015-1-20,
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戚栋明, 曹俊, 高玉洁, 曹志海. 聚硅氧烷/钛溶胶光催化复合膜的光催化降解作用[J]. 高分子学报, 2015,(1):1-7.
Dong-ming Qi, Jun Cao, Yu-jie Gao, Zhi-hai Cao. Photocatalysis of Polysiloxane/Titanium Sol Photocatalytic Composite Films[J]. Acta Polymerica Sinica, 2015,(1):1-7.
戚栋明, 曹俊, 高玉洁, 曹志海. 聚硅氧烷/钛溶胶光催化复合膜的光催化降解作用[J]. 高分子学报, 2015,(1):1-7. DOI: 10.11777/j.issn1000-3304.2015.14148.
Dong-ming Qi, Jun Cao, Yu-jie Gao, Zhi-hai Cao. Photocatalysis of Polysiloxane/Titanium Sol Photocatalytic Composite Films[J]. Acta Polymerica Sinica, 2015,(1):1-7. DOI: 10.11777/j.issn1000-3304.2015.14148.
以锐钛型的钛溶胶和粉体TiO2为光催化材料
以聚硅氧烷(PDMS)和聚丙烯酸酯(PA)为黏合剂
制得相应的光催化复合膜.通过X-射线衍射分析、粒度分析、电镜观察等手段比较2种TiO2颗粒的晶型及其在有机介质和复合膜中的分散状态
通过光学显微观察、载体降解失重评估、染液吸光度测定等方式考察TiO2对两类黏合剂和酸性品红6B染料分子的光催化降解作用.发现溶胶-凝胶法可制得结晶程度较高的锐钛型钛溶胶
且所制颗粒晶粒更小、与有机介质和黏合剂的相容性更好
在复合膜中分散更均匀
因而更易光催化降解接近复合膜的染料分子
但同时也更易老化降解以低键能CC键为主链的常规碳链黏合剂.而聚硅氧烷以高键能的SiO键为主链
其抵御光催化所产高能自由基的氧化-还原作用的能力更强
是一种理想的光催化有机载体.通过聚硅氧烷与钛溶胶的有效复合
可在保证复合膜稳定性的同时赋予其更强的光催化降解作用.
A series of photocatalytic composite films were prepared by using anatase titanium sol or P25 type TiO2 powders as photocatalytic materials
and polysiloxane (PDMS) or polyacrylate (PA) as binders.The crystalline phase and dispersion of the two TiO2 particles in organic media (toluene and polymeric matrixes) and photocatalytic degradation of organic matrixes by TiO2 particles were characterized by X-ray diffraction analysis
particle size analysis
field emission scanning electron microscopy
transmission electron microscopy
3D optical microscopy
weight loss evaluation and UV-Vis spectroscopy
respectively.In addition
photocatalytic activity of PMDS/TiO2 composite films was evaluated by photocatalytic degradation of acid fuchsine 6B under UV irradiation.Titanium sol prepared via sol-gel process was composed of small crystalline grains with a size of about 3 nm
and indeed displayed a higher crystallinity.In comparison to P25 type TiO2
the titanium sol revealed a better compatibility with organic media.They could be uniformly dispersed in organic media without aggregation.Therefore
compared with the composite film with P25 type TiO2
the CC based polymeric matrix was degraded more seriously in the composite films with titanium sol due to their better photocatalytic ability and better dispersion.In contrast
the SiO bonds in the main chain of polysiloxane could resist the strong oxidation of high-energy radicals derived from photocatalytic titaniumsol.Thus
polysiloxane can be used as an ideal photocatalytic organic matrix to load titanium sol
and a kind of composite films with a strong photocatalytic activity and high stability can be obtained.
聚硅氧烷钛溶胶复合膜光催化
PolysiloxaneTitanium solComposite filmPhotocatalysis
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