Jia-qiang Jing, Na-na Sun, Yun-peng An, Wen-bo Jin, Zhen Tian. Salt Resistance of Compound Systems for Amphoteric Surfactant and HPAM[J]. Acta Polymerica Sinica, 2015,(1):88-96.
Jia-qiang Jing, Na-na Sun, Yun-peng An, Wen-bo Jin, Zhen Tian. Salt Resistance of Compound Systems for Amphoteric Surfactant and HPAM[J]. Acta Polymerica Sinica, 2015,(1):88-96. DOI: 10.11777/j.issn1000-3304.2015.14158.
Considering the salt sensitivity of HPAM and the salt resistance of amphoteric surfactant dodecyl dimethyl betaine
this work explored the effects of the surfactant and inorganic salt concentrations and pH values on the laws of viscosities of the compound systems by using the single factor experiments.The experimental results show that the viscosities of the systems change a little while the concentrations of the amphoteric surfactant are lower than the critical association concentration (CAC)
but they increase sharply as the concentrations of the amphoteric surfactant increase above CAC
reach to a peak when the surfactant concentration equals to the polymer saturation concentration (PSP) and decrease with the network structure of the system broken by continuously adding the surfactant.Inorganic salt show a twofold effect on the viscosities of the compound systems
increasing within the low salt concentration and decreasing above the high concentration of salt.At different pH
the salt resistance is presented as alkaline (pH=11.4) acidity (pH=2.8) neutral(pH=7).In order to further explore the effect degree of the concentrations of polymer
amphoteric surfactant and inorganic salt for the system viscosities
this work has done nonlinear regression of the uniform experimental data by using SPSS software
gotten a quantitative relation of the compound system viscosity with three parameters and analyzed their effects on the salt resistance of the compound systems. The theoretical model shows that the polymer concentration is the most important factor
and the effects of the concentrations of amphoteric surfactant and inorganic salt on the system viscosities are similar to those of their single-factors.