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高分子材料工程国家重点实验室 四川大学高分子研究所,成都,610065
纸质出版日期:2015-11-20,
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向明, 蔡燎原, 曹亚, 亢健, 吴桐. 干法双拉锂离子电池隔膜的制造与表征[J]. 高分子学报, 2015,(11):1235-1245.
Ming Xiang, Liao-yuan Cai, Ya Cao, Jian Kang, Tong Wu. Manufacturing and Characterization of Polypropylene Separators for Lithium Ion Battery via Biaxially Stretching Method[J]. Acta Polymerica Sinica, 2015,(11):1235-1245.
向明, 蔡燎原, 曹亚, 亢健, 吴桐. 干法双拉锂离子电池隔膜的制造与表征[J]. 高分子学报, 2015,(11):1235-1245. DOI: 10.11777/j.issn1000-3304.2015.15165.
Ming Xiang, Liao-yuan Cai, Ya Cao, Jian Kang, Tong Wu. Manufacturing and Characterization of Polypropylene Separators for Lithium Ion Battery via Biaxially Stretching Method[J]. Acta Polymerica Sinica, 2015,(11):1235-1245. DOI: 10.11777/j.issn1000-3304.2015.15165.
总结了对-PP铸片晶片分布的均匀性进行快速评价
进而衡量隔膜的孔径分布、厚度分布均匀性的最新研究思路和进展.相关研究通过精确控制结晶温度制备了5组具有相似结晶度、高晶含量但是不同晶片厚度分布的-PP流延铸片
并对其晶片的厚度分布情况进行分析.对其进行拉伸测试
发现了其应力应变曲线出现奇特的二次屈服现象.通过对-PP在不同拉伸阶段的结构形态进行详细表征
得出二次屈服点是折叠链晶片拉直转化为无定型相的过渡点.同时发现晶晶片分布越窄
二次屈服出现时的应变值就越大.另一方面
对铸片进行双向拉伸制备隔膜
发现晶片分布越窄的铸片生产的隔膜孔径分布就越窄.退火热处理后的拉伸测试也进一步验证了此规律.因此
可利用室温下的单轴拉伸测试对-PP流延铸片内部晶片分布宽度
以及其所制备隔膜的孔径分布进行简单而有效地评价.
This manuscript reviews the latest progress to characterize the uniformity of lamellar thickness
the tensile behavior and the uniformity of cavitation during stretching of the casting film
and further to predict the pore size distribution and thickness distribution of the final separator.Five -PP precursor films
which had similar crystallinity and extremely high contents of -crystals
but different lamellar thickness distribution
were prepared through crystallizing at different temperatures.In the tensile test
we first discovered a peculiar double yield phenomenon in -PP under tensile loading.Based on the detailed characterization of morphological evolution during stretching
we concluded that the second yield point corresponds to the transition point where the lamellae began to transform into amorphous phase.Meanwhile
a narrower -lamellar thickness distribution would result in a homogeneous deformation
delayed occurrence of second yield point and a more uniform pore size distribution in the porous membrane.In addition
the stress-strain behaviors of -PP after annealing treatments also verified the trend above.Therefore
the uniaxial tensile testing can be used to evaluate the lamellar thickness distribution of -PP cast films efficiently.
聚丙烯二次屈服晶片分布宽度孔径分布均匀性
-Nucleated polypropyleneDouble yielding behaviorLamellar thickness distributionPore size distribution
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