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1. 西南石油大学材料科学与工程学院 新能源材料及技术研究中心,成都,610500
2. 中国科学院成都有机化学研究所,成都,610041
纸质出版日期:2016-4-20,
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武元鹏, 周昌亮, 郭凌江, 杨浩, 林元华, 郑朝晖, 丁小斌. 基于聚氨酯的磁性碳化泡沫的制备及其吸油性能研究[J]. 高分子学报, 2016,(4):402-408.
Yuan-peng Wu, Chang-liang Zhou, Ling-jiang Guo, Hao Yang, Yuan-hua Lin, Zhao-hui Zheng, Xiao-bin Ding. Preparation and Oil Absorption of Magnetically Carbonized Foams Based on Waste Polyurethane Foams[J]. Acta Polymerica Sinica, 2016,(4):402-408.
武元鹏, 周昌亮, 郭凌江, 杨浩, 林元华, 郑朝晖, 丁小斌. 基于聚氨酯的磁性碳化泡沫的制备及其吸油性能研究[J]. 高分子学报, 2016,(4):402-408. DOI: 10.11777/j.issn1000-3304.2016.15341.
Yuan-peng Wu, Chang-liang Zhou, Ling-jiang Guo, Hao Yang, Yuan-hua Lin, Zhao-hui Zheng, Xiao-bin Ding. Preparation and Oil Absorption of Magnetically Carbonized Foams Based on Waste Polyurethane Foams[J]. Acta Polymerica Sinica, 2016,(4):402-408. DOI: 10.11777/j.issn1000-3304.2016.15341.
以废弃聚氨酯泡沫(PUF)为原料
在其表面依次修饰聚丙烯酸(PAA)、Fe3+
然后在230℃条件下
通过高温碳化处理
制备了具有多孔结构的磁性碳化泡沫材料.用光学显微镜、红外吸收光谱(FTIR)、X-射线衍射(XRD)、接触角对磁性碳化泡沫进行表征.详细考察了AA含量、Fe3+浓度对材料吸附容量、吸附速率的影响.材料具有明显的亲油、疏水特性
对各种有机溶剂和油类分子吸附容量都在10 g/g以上
而且在5 min内就可吸附饱和
同时材料密度小
可漂浮于水面对有机溶剂进行快速吸附
并通过外界磁场实现快速分离.因此
该材料在原油泄漏处理、油水分离、油田采出液处理、工业污水净化等领域具有重要的应用价值.
In this work
the waste polyurethane foams were recycled and used as precursors to fabricate magnetically carbonized foams which exhibited effectively oil absorption and magnetic responsive preporties through a facile approach.Polyurethane foams were firstly dipped into acrylic acid (AA) aqueous solution to be modified with PAA on the surface of their pores by using solution polymerization.Then the foams were immersed into FeCl3 aqueous solution for soaking Fe3+ until saturation.Subsequently
the composite materials were heated to 230℃ and kept at that temperatue under the protection of nitrogen for 4 h to form magnetically carbonized foams.The effects of concentrations of AA and FeCl3
and heat temperature on the performances of magnetically carbonized foams were investigated in detail.The results of optical microscopy show that the as-fabaricated foams are porous.The data of Fourier transform infrared spectroscopy depict that the foams are modified by PAA and Fe3+.X-ray diffraction patterns demonstrate that Fe3+ changes to Fe3O4 after heating.The contact angles of water on the foams increased from 80.8 to 115.4.Optimized magnetically carbonized foams can absorb oil more than 10 times of their own weight and can quickly absorb oil within 5 min.Importantly
the density of the foams are low so that they can float on the surface of water for treating oil spills.And the foams absorbing oil can be easily seperated by a magnet.The magnetically carbonized foams synthesized in this work are good candidates for oil spill absorption and oil-water seperation.
聚氨酯泡沫磁性碳化材料吸油材料
Polyurethane foamsMagnetic foamsOil absorption
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