表面引发聚合新进展及应用

李斌; 于波; 周峰

doi:10.11777/j.issn1000-3304.2016.16198

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表面引发聚合新进展及应用

专论 | 更新时间：2021-03-19

- 表面引发聚合新进展及应用
- Recent Advances and Applications in Surface-initiated Polymer Brushes
- 高分子学报 2016年第10期页码：1312-1329
- 作者机构：
  
  中国科学院兰州化学物理研究所固体润滑国家重点实验室兰州 730000
- 作者简介：
  
  周峰,E-mail:zhouf@licp.cas.cn Feng Zhou,E-mail:zhouf@licp.cas.cn
- 基金信息：
  
  国家自然科学基金(基金号51573199，21434009)
- DOI：10.11777/j.issn1000-3304.2016.16198
  中图分类号：
- 纸质出版日期：2016-10，
  
  收稿日期：2016-6-23，
  
  修回日期：2016-8-3，
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李斌, 于波, 周峰. 表面引发聚合新进展及应用[J]. 高分子学报, 2016,(10):1312-1329.

Li Bin, Yu Bo, Zhou Feng. Recent Advances and Applications in Surface-initiated Polymer Brushes[J]. Acta Polymerica Sinica, 2016,(10):1312-1329.
李斌, 于波, 周峰. 表面引发聚合新进展及应用[J]. 高分子学报, 2016,(10):1312-1329. DOI： 10.11777/j.issn1000-3304.2016.16198.

Li Bin, Yu Bo, Zhou Feng. Recent Advances and Applications in Surface-initiated Polymer Brushes[J]. Acta Polymerica Sinica, 2016,(10):1312-1329. DOI： 10.11777/j.issn1000-3304.2016.16198.

摘要

综述了近年来聚合物刷合成与应用方面的新进展.简要介绍了利用表面引发原子转移自由基聚合（SI-ATRP）制备聚合物刷的历程和重要进展.重点论述了通过电化学、光诱导以及牺牲阳极技术、仿生合成等发展了多种表面引发ATRP新方法，基于如何将聚合物从分子尺度过渡到微米尺度的思考，实现了多尺度聚合物刷结构的制备.简要综述了聚合物刷在以下3个方面的应用研究：（1）智能驱动，利用聚合物刷构象变化，实现微悬臂驱动、辅助放大的电驱动以及仿毛毛虫运动.（2）生物润滑，利用聚合物的环境响应行为实现了对摩擦系数的调控，并发展了球刷型润滑材料.（3）表面防污，表面接枝含离子液体官能团的聚合物刷，并与仿生技术相结合，利用化学组成和结构化协同效应，得到一系列高性能低毒海洋防污界面材料.

Abstract

Recent advances in surface-initiated polymer brushes and specific applications in various research fields are reviewed

the development of surface-initiated atom radical polymerization (SI-ATRP) is highlighted.The general surface modification method is described in detail to realize functional modification on almost all substrates.The combination of the surface-initiated polymerization with other soft lithography techniques

e.g

micro-contacting printing enables the easy surface functionalization with various surface morphologies such as pattern and gradient.The fundamental mechanistic and synthetic features of SI-ATRP are discussed and some new techniques particularly external-stimuli mediated catalytic and initiation systems are highlighted

including electrochemistry

chemical reducing agents and photochemistry

which have many potential applications in fields such as lubrication

anti-fouling and so on.These methods have solved problems occurring in traditional SI-ATRP

such as inert atmosphere protection

poor controllability

difficulty to recycle monomers

and single modification of substrates.Besides

polymer brush with micrometer scale prepared by using anodic aluminium oxide as a template create multi-scale structures on surfaces.Applications of polymer brush are reviewed mainly in three aspects in this review.(1) Smart actuation:external-stimuli responsive polymer brushes coated substrates can be used as a smart actuator due to the conformation changes of the polymer chains when surrounding environment changes

for example

performing the worm-like movements.(2) Bio-lubrication:polymer brushes have been used as effective lubricating materials on surfaces and the frictional coefficient can be regulated by changing the solvent conditions.(3) Antifouling:Polyelectrolyte brush grafted substrates have been found many applications in biological fields such as antifouling coatings

a series of high performance

low toxicity marine antifouling materials have been developed by taking the advantages of the synergistic effect of the unique surface compositions and structures of polymer brushes.In all

newly developed external stimuli regulated surface-initiated ATRP methods are presented to show how they can be advantageously used to produce multi-functional polymer brushes

which have been widely used as advanced coatings to modify surface properties.

关键词

聚合物刷表面修饰原子转移自由基聚合外界调控

Keywords

Polymer brushSurface modificationAtom transfer radical polymerizationExternal stimulus

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