高性能聚合物光伏材料的设计与应用

姚惠峰; 侯剑辉

doi:10.11777/j.issn1000-3304.2016.16216

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高性能聚合物光伏材料的设计与应用

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- 高性能聚合物光伏材料的设计与应用
- Design and Application of Highly Efficient Polymers for Polymer Solar Cells
- 高分子学报 2016年第11期页码：1468-1481
- 作者机构：
  
  1.中国科学院化学研究所北京分子科学国家实验室高分子物理与化学国家重点实验室北京 100190
  2.中国科学院大学北京 100049
- 作者简介：
  
  [ "侯剑辉,男,1978年2月生,中国科学院化学研究所研究员,北京科技大学兼职教授,博士生导师.2001年于北京科技大学化学系获学士学位,2006年于中国科学院化学研究所获博士学位(导师:李永舫);2006~2008年于美国加州大学洛杉矶分校Yang Yang教授课题组做博士后研究,随后在美国朔纶能源公司任研究部门主管;2010年入选中国科学院化学研究所\"引进国外杰出青年人才计划\".2013年获得国家杰出青年科学基金资助,2014年被选为\"万人计划\"青年拔尖人才;2015年获得中国科学院青年科学家奖.主要研究兴趣为有机太阳能电池材料的设计和应用" ]
- 基金信息：
  
  国家自然科学基金（基金号21325419）、重大研究计划重点项目（项目号91333204）和面上项目（项目号51173189）、国家重点基础研究发展计划（973计划，项目号2014CB643501）和中国科学院百人计划的经费支持()
- DOI：10.11777/j.issn1000-3304.2016.16216
  中图分类号：
- 纸质出版日期：2016-11，
  
  收稿日期：2016-6-29，
  
  修回日期：2016-7-26，
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姚惠峰, 侯剑辉. 高性能聚合物光伏材料的设计与应用[J]. 高分子学报, 2016,(11):1468-1481.

Hui-feng Yao, Jian-hui Hou. Design and Application of Highly Efficient Polymers for Polymer Solar Cells[J]. Acta Polymerica Sinica, 2016,(11):1468-1481.
姚惠峰, 侯剑辉. 高性能聚合物光伏材料的设计与应用[J]. 高分子学报, 2016,(11):1468-1481. DOI： 10.11777/j.issn1000-3304.2016.16216.

Hui-feng Yao, Jian-hui Hou. Design and Application of Highly Efficient Polymers for Polymer Solar Cells[J]. Acta Polymerica Sinica, 2016,(11):1468-1481. DOI： 10.11777/j.issn1000-3304.2016.16216.

摘要

高性能聚合物光伏材料对于推动聚合物太阳能电池领域的发展具有十分重要的作用.随着研究的深入，聚合物光伏材料从早期的聚噻吩体系逐步发展到具有推拉电子作用的给体-受体（D-A）交替共聚物，其相应的器件光伏效率也从最初的1%左右提升到如今超过11%.近十年来，种类繁多的给受体单元被开发并应用于聚合物材料的构建中，其中基于苯并二噻吩（BDT）单元的聚合物材料因为具有良好的光伏性能，得到了十分广泛的应用.近年来，非富勒烯受体的迅速发展给聚合物太阳能电池的研究注入了新的活力，BDT类聚合物在基于非富勒烯受体的聚合物太阳能电池中也展现出重要的作用，已经获得了超过11%的光电转化效率.本文简要介绍了我们在高性能聚合物光伏材料的设计与应用中的相关工作，主要分为聚噻吩和苯并二噻吩材料的设计与应用、活性层形貌调控以及非富勒烯聚合物太阳能电池的相关研究.

Abstract

Polymer solar cell (PSC) with bulk heterojunction structure has attracted considerable attention due to its potential for harnessing low-cost solar energy and making flexible devices.The design and application of highly efficient conjugated polymers has enabled the rapid progress in the development of organic photovoltaic technology

and the power conversion efficiency (PCE) has been boosted to over 11%.A highly efficient polymer donor should possess several intrinsic features

such as a broad absorption spectrum with high extinction coefficient

suitable molecular energy level alignment of the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) levels to afford a sufficient driving force for efficient charge separation with minimum energy loss

high charge mobilities to facilitate charge transport and favorable blend morphology to facilitate exciton diffusion and charge separation.From early homopolymer polythiophene system to typical donor-acceptor (D-A) structure polymers

many conjugated polymer donors have been developed and applied in fabricating PSC device.In this review

we first summarize some of our works from the polythiophene with the two conjugated side chains to benzodithiophene (BDT)-based D-A polymers.Since the blend morphology plays a vital role in determining the performance of the PSC device

we also did some works about the morphology optimization from the aspect of molecular design.Recently

fullerene-free PSC has emerged as a new horizon in the field of PSC

and we have demonstrated fullerene-free PSC device with PCE over 11% by using BDT-based polymer.In addition

we also summarize some other works about the fullerene-free PSC in our group.In the end

after a brief summary

we present some inevitable questions about the development of commercial PSC

such as the efficiency

stability

manufacturability and reproducibility.From the materials and processing methods

we think these problems can be solved and except that PSC has real applications in the near future.

关键词

聚合物太阳能电池光电转化效率分子设计聚噻吩苯并二噻吩

Keywords

Polymer solar cellMolecular designPolythiopheneBenzodithiophene

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