机械力诱导发光高分子材料

袁伟; 袁媛; 陈于蓝

doi:10.11777/j.issn1000-3304.2016.16223

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机械力诱导发光高分子材料

专论 | 更新时间：2021-03-19

- 机械力诱导发光高分子材料
- Mechanoluminescent Polymers
- 高分子学报 2016年第11期页码：1495-1507
- 作者机构：
  
  分子光电科学天津市重点实验室天津大学天津 300354
- 作者简介：
  
  [ "陈于蓝,女,1983年1月生.2005年本科毕业于吉林大学化学学院.2010年获中国科学院化学研究所高分子化学与物理专业博士学位.2010年至2014年先后在荷兰埃因霍温理工大学与德国马普高分子研究所从事博士后工作.2014年9月至今,任天津大学理学院研究员、博士生导师.2015年入选\"国家青年千人计划\",获国家自然科学基金委优秀青年科学基金资助.研究方向为高分子机械力化学与机械力响应性高分子" ]
- 基金信息：
  
  国家自然科学基金(（基金号51503142）资助项目)
- DOI：10.11777/j.issn1000-3304.2016.16223
  中图分类号：
- 纸质出版日期：2016-11，
  
  收稿日期：2016-7-6，
  
  修回日期：2016-7-22，
扫描看全文
袁伟, 袁媛, 陈于蓝. 机械力诱导发光高分子材料[J]. 高分子学报, 2016,(11):1495-1507.

Wei Yuan, Yuan Yuan, Yu-lan Chen. Mechanoluminescent Polymers[J]. Acta Polymerica Sinica, 2016,(11):1495-1507.
袁伟, 袁媛, 陈于蓝. 机械力诱导发光高分子材料[J]. 高分子学报, 2016,(11):1495-1507. DOI： 10.11777/j.issn1000-3304.2016.16223.

Wei Yuan, Yuan Yuan, Yu-lan Chen. Mechanoluminescent Polymers[J]. Acta Polymerica Sinica, 2016,(11):1495-1507. DOI： 10.11777/j.issn1000-3304.2016.16223.

摘要

发展具有机械力诱导发光性质的高分子是目前高分子力化学领域的一个新兴前沿课题.这类响应性高分子材料由于能够将机械能转换成灵敏的光信号，是连接微观分子水平研究与宏观材料性能表征的桥梁，因而有望作为高灵敏（在空间和时间2个维度上）应力探针在高分子材料损伤探测与失效机理研究方面发挥重要作用.本文详细介绍了机械力诱导发光高分子的设计与合成策略，以及研究者对发光机理的探索、发光效率的优化、发光过程的应用，揭示这类高分子的发光特点及其作为应力探针的优势，归纳总结已取得的初步进展，并对这类新型响应性高分子材料的发展进行简单的评述和展望.

Abstract

The development of mechanoluminescent polymers is one of the emerging and frontier subjects in the field of polymer mechanochemistry.This important research effort has been driven by the need for advanced stress probes to report rare molecular scission events that precede failure in polymers.What is already known is that the stress-induced scission of chemical bonds often plays a critical role in failure initiation state

thus

precise location and timing of chain-scission events during fracture are although difficult in practice

yet key to understanding failure mechanisms.If these rare failure initiation events could be well characterized and cast in the language of organic and physical organic chemistry

opportunities for preventing and ameliorating early failure events will be obtained

and rational molecular strategies for advanced polymeric materials will result.Stimuli-responsive polymers

that can convert mechanical force into sensitive light signal

represent a unique platform that opens the way to the detailed study of the specific molecular failure events and the macroscopic properties of polymers

and therefore

are considered as a versatile spectroscopic probe capable of sensing and mapping deformations

stresses and damage in different polymer architectures with high spatial and temporal resolutions.In this review

the strategies for the design and synthesis of mechanoluminescent polymers

and the great efforts towards the understanding of the mechanisms of such mechanically induced light from polymers

the approaches to fine-tune the optophysical properties of the light (including light intensity

colour of light emission

and the force thresholds of light)

as well as the applications of mechanoluminescence to probe the failure of different polymers are comprehensively introduced.The unique features of mechanoluminescence from polymers and the advantages of these polymers as sensitive stress probes over other responsive polymers with measureable output are revealed.The progress achieved up to now is summarized

and a short outlook concerning the development of mechanoluminescent polymers is provided.

关键词

刺激响应高分子高分子力化学机械力诱导发光12-二氧环丁烷应力探针

Keywords

Stimuli-responsive polymerPolymer mechanochemistryMechanoluminescence12-DioxetaneStress probe

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