基于冠醚和柱芳烃主客体识别的超分子聚合物材料

吉晓帆; 夏丹玉; 颜徐州; 王虎; 黄飞鹤

doi:10.11777/j.issn1000-3304.2017.16167

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基于冠醚和柱芳烃主客体识别的超分子聚合物材料

专论 | 更新时间：2021-03-12

- 基于冠醚和柱芳烃主客体识别的超分子聚合物材料
- Supramolecular Polymer Materials Based on Crown Ether and Pillararene Host-Guest Recognition Motifs
- 高分子学报 2017年第1期页码：9-18
- 作者机构：
  
  浙江大学化学系杭州 310027
- 作者简介：
  
  黄飞鹤,男,1973年2月生2005年3月获弗吉尼亚理工大学博士学位2005年12月起任浙江大学教授主要从事基于主客体分子识别构筑超分子聚合物研究主要奖励和荣誉有:2011年国家杰出青年科学基金资助,指导博士生获2011年全国百篇优秀博士论文提名奖,2012年入选英国皇家化学会会士,2013年入选亚洲化学大会Asian Rising Star,2014年中国化学会-阿克苏诺贝尔化学奖,2015年英国皇家化学会Cram Lehn Pedersen Prize in Supramolecular Chemistry,2016年英国皇家化学会Polymer Chemistry Lectureship Award,2016年入选国家万人计划领军人才,E-mail:fhuang@zju.edu.cn
- 基金信息：
  
  国家重点基础研究发展计划（973计划）子课题(项目号2013CB834502);国家自然科学基金(基金号21125417，21434005，91527301)
- DOI：10.11777/j.issn1000-3304.2017.16167
  中图分类号：
- 纸质出版日期：2017-1，
  
  收稿日期：2016-5-11，
  
  修回日期：2016-6-22，
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吉晓帆, 夏丹玉, 颜徐州, 王虎, 黄飞鹤. 基于冠醚和柱芳烃主客体识别的超分子聚合物材料[J]. 高分子学报, 2017,(1):9-18.

Ji Xiao-fan, Xia Dan-yu, Yan Xu-zhou, Wang Hu, Huang Fei-he. Supramolecular Polymer Materials Based on Crown Ether and Pillararene Host-Guest Recognition Motifs[J]. Acta Polymerica Sinica, 2017,(1):9-18.
吉晓帆, 夏丹玉, 颜徐州, 王虎, 黄飞鹤. 基于冠醚和柱芳烃主客体识别的超分子聚合物材料[J]. 高分子学报, 2017,(1):9-18. DOI： 10.11777/j.issn1000-3304.2017.16167.

Ji Xiao-fan, Xia Dan-yu, Yan Xu-zhou, Wang Hu, Huang Fei-he. Supramolecular Polymer Materials Based on Crown Ether and Pillararene Host-Guest Recognition Motifs[J]. Acta Polymerica Sinica, 2017,(1):9-18. DOI： 10.11777/j.issn1000-3304.2017.16167.

摘要

超分子聚合物材料是高分子科学、超分子化学和材料科学3个学科相结合的产物.通过精妙的设计，我们不仅可以赋予它传统高分子材料所拥有的光学、电学以及力学等性能，同时还可以使其具有超分子材料的动态可逆性和刺激响应性.已用于构筑超分子聚合物材料的主客体识别体系有很多，从识别体系中的主体来说，包括基于冠醚、环糊精、杯芳烃、葫芦脲、柱芳烃等大环的主客体体系.其中，冠醚作为第一代大环主体，它的模板合成直接开辟了超分子化学这一领域，而柱芳烃是最近发展起来的一类新的大环主体，它具有刚性的骨架，并且制备简单，容易功能化，同样也受到超分子化学家们的广泛关注.本文着重综述了我们课题组基于冠醚和柱芳烃主客体识别所构筑的超分子聚合物材料.在这些材料的制备中，我们利用了主客体识别的刺激响应性、可逆性和选择性，来实现对这类材料的组装结构以及功能的精确调控.

Abstract

Supramolecular polymer materials

which have emerged as the marriage of polymer science

supramolecular chemistry and materials science

have gained considerable interest in recent years as excellent materials not only due to their properties similar to traditional polymers which are built by covalent bonds

but also because of the reversibility and stimuli-responsiveness of noncovalent bonds. As a result

the reversibility and responsiveness to external stimuli may further provide a range of potential applications

including those as superabsorbers

as matrices in analytical chemistry or biology

and as storage and delivery systems for active substances in the biomedical field. Various kinds of noncovalent interactions can be introduced into polymer materials

such as hydrogen bonding

aromatic stacking interactions

metal coordination

and host-guest interactions. Among them

host-guest interactions have been widely used in the construction of functional supramolecular polymer materials

because they usually combine multiple noncovalent interactions

such as hydrogen bonding

aromatic stacking interactions

charge transfer

and hydrophobic interactions between two complementary compounds

making them not only show good binding affinity

but also form complexes with fixed host-guest geometry and directionality. Moreover

macrocycle-based supramolecular polymer materials can response to abundant external stimuli

such as pH change

photo irradition

anions

cations

temperature

and solvent. Furthermore

macrocycle-based supramolecular polymer materials can be prepared under different conditions

namely in solution

in gel

and in the solid state. Macrocyclic hosts

including crown ethers

cyclodextrins

calixarenes

cucurbiturils

and pillararenes

are the most commonly used building blocks in the fabrication of supramolecular polymer materials. Crown ethers

the first generation of artificial supramolecular hosts

have been utilized to construct various supramolecular polymer materials. Moreover

pillararenes

a kind of novel supramolecular hosts

have shown novel properties and functionalities. In this paper

we stated the utilization of crown ether and pillararene host-guest recognition motifs to control the self-assembly of traditional polymers in order to fabricate supramolecular polymer materials.

关键词

主客体识别超分子聚合物自组装冠醚柱芳烃

Keywords

Host-Guest recognition motifsSupramolecular polymer materialsSelf-assemblyCrown ethersPillararenes

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