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AB
g 型单体超支化聚合反应的理论模型Theoretical Model of Hyperbranched Polymerization with AB
g Type Monomer- 高分子学报 2017年第2期 页码：143-154
- 作者机构：
江苏大学材料科学与工程学院 镇江 212013
- 作者简介：
周志平，男，1958年3月生，江苏大学材料科学与工程学院教授. 1981年毕业于镇江师范专科学校物理系；1989年毕业于杭州大学物理系，获硕士学位；1998年毕业于上海交通大学化学化工学院，获博士学位. 2001年5月至2003年7月日本学术振兴会外国人特别研究员及日本东京工芸大学客座教授.主要从事超支化聚合反应动力学理论、高分子构象统计、功能高分子材料等方向的研究工作，迄今发表学术论文160多篇. 2009年合作获得国家自然科学二等奖. E-mail: zhouzp@ujs.edu.cn Zhi-ping Zhou, E-mail:zhouzp@ujs.edu.cn
- 基金信息：国家自然科学基金(21174057)
DOI：10.11777/j.issn1000-3304.2017.16226
中图分类号：纸质出版日期：2017-2-20，
收稿日期：2016-7-7，
修回日期：2016-8-9，
扫 描 看 全 文
周志平, 郝桐帆. AB
g 型单体超支化聚合反应的理论模型[J]. 高分子学报, 2017,(2):143-154.Zhou Zhi-ping, Hao Tong-fan. Theoretical Model of Hyperbranched Polymerization with AB
g Type Monomer[J]. Acta Polymerica Sinica, 2017,(2):143-154.周志平, 郝桐帆. AB
g 型单体超支化聚合反应的理论模型[J]. 高分子学报, 2017,(2):143-154. DOI： 10.11777/j.issn1000-3304.2017.16226.Zhou Zhi-ping, Hao Tong-fan. Theoretical Model of Hyperbranched Polymerization with AB
g Type Monomer[J]. Acta Polymerica Sinica, 2017,(2):143-154. DOI： 10.11777/j.issn1000-3304.2017.16226.
摘要
超支化聚合物的可控制备与分子设计对其工业化应用是十分重要的，这有待于弄清超支化聚合物的形成机理.本文回顾了早期关于超支化聚合物的Flory-Stockmayer理论，重点介绍与AB
g
型单体相关的超支化聚合反应的动力学原理，这是我国科学家在这一领域的工作亮点，在国际上受到了广泛的关注.相比其它一些理论方法，聚合反应动力学理论原理清晰，可通过解动力学微分方程导出反应产物的平均支化度和聚合度分布函数的解析式，由此可以计算各种分子参数，为超支化聚合物的分子设计和可控制备提供了理论基础.
Abstract
Molecular design and controllable preparation of hyperbranched polymers are of great significance for their industrialized application
which depends on the understanding for their formation mechanism. At the end of 1980's
Kim
et al
. successfully prepared hyperbranched polyphenylenes. Since then
the hyperbranched polymers have been a hot topic in polymer science and great progress has been made in both experiments and theory. The topological structure and molecular parameters can be estimated by the theory of hyperbranched polymers
which provided a great help to the molecular design and controllable preparation of hyperbranched polymers. Among the various theoretical models
kinetics of hyperbranched polymerization is the most perfect due to the clear principle and rigorous derivation
by which the analytical expressions of the molecular weight distribution functions and the various molecular parameters of the products can be derived. It is one of highlights of scientists working in China. The polymerization of AB
g
type monomer is one of the most important technologies to prepare the hyperbranched polymers. However
the molecular weight distribution is extremely wide for the products of the polycondensation with pure AB
g
type monomer. The presence of a little of multifunctional group can narrow the molecular weight distribution. Moreover
the polydispersity of hyperbranched polymers obtained can drastically decrease when the monomers are slowly added to the reaction system. Another deficiency of the hyperbranched polymers resulted from the polycondensation with pure AB
g
type monomer is the poor mechanical properties. One of the improved approaches is the copolymerization of AB and AB
g
monomers
in which some linear segments can be incorporated into the hyperbranched polymer obtained. Thus
the degree of branching and the mechanical properties of the polymer can be designed by suitable monomer feed ratio. Taking account of the substitution effect
various degree of branching of the products also can be understood. Yan
et al
. developed kinetic model for a large variety of hyperbranched polymerizations and successfully explained these phenomena mentioned above. In this work
the early Flory-Stockmayer theory for hyperbranched polymers is reviewed and
specially
the kinetic theory of hyperbranched polymerization with AB
g
type monomer is introduced.
关键词
超支化聚合物聚合反应动力学分子量分布函数支化度
Keywords
Hyperbranched polymerPolymerization kineticsMolecular weight functionDegree of branching
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