超分子有机框架:具有周期性孔结构的超分子聚合物

王辉; 张丹维; 黎占亭

doi:10.11777/j.issn1000-3304.2017.16234

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超分子有机框架:具有周期性孔结构的超分子聚合物

专论 | 更新时间：2021-03-12

- 超分子有机框架:具有周期性孔结构的超分子聚合物
- Supramolecular Organic Frameworks: Porous Periodic Supramolecular Polymers
- 高分子学报 2017年第1期页码：19-26
- 作者机构：
  
  复旦大学化学系上海 200433
- 作者简介：
  
  黎占亭,男,1966年7月生1985年毕业于郑州大学化学系,1992年在中科院上海有机化学研究所获博士学位(导师:陈庆云研究员),先后在南丹麦大学和美国伊利诺伊大学做博士后研究1993~2010年任上海有机所副研究员和研究员,现任复旦大学化学系教授主要从事物理有机、超分子化学和有机孔材料研究,E-mail:ztli@fudan.edu.cn
- 基金信息：
  
  国家自然科学基金(21432004;91527301)
- DOI：10.11777/j.issn1000-3304.2017.16234
  中图分类号：
- 纸质出版日期：2017-1，
  
  收稿日期：2016-7-22，
  
  修回日期：2016-8-11，
扫描看全文
王辉, 张丹维, 黎占亭. 超分子有机框架:具有周期性孔结构的超分子聚合物[J]. 高分子学报, 2017,(1):19-26.

Wang Hui, Zhang Dan-wei, Li Zhan-ting. Supramolecular Organic Frameworks: Porous Periodic Supramolecular Polymers[J]. Acta Polymerica Sinica, 2017,(1):19-26.
王辉, 张丹维, 黎占亭. 超分子有机框架:具有周期性孔结构的超分子聚合物[J]. 高分子学报, 2017,(1):19-26. DOI： 10.11777/j.issn1000-3304.2017.16234.

Wang Hui, Zhang Dan-wei, Li Zhan-ting. Supramolecular Organic Frameworks: Porous Periodic Supramolecular Polymers[J]. Acta Polymerica Sinica, 2017,(1):19-26. DOI： 10.11777/j.issn1000-3304.2017.16234.

摘要

本文概述了水相周期性超分子有机框架（supramolecular organic frameworks，SOFs）的研究进展.首先介绍了水相超分子聚合物和多孔材料研究的背景，然后分别描述了二维单层、三维金刚石型和立方型SOF的构建、结构表征及功能.最后就SOF的未来应用前景做出了分析和展望.

Abstract

Porous materials have found extensive applications in

such as

adsorption

separation

catalysis

transport and bio-imaging. In the past two decades

metal-organic frameworks and covalent-organic frameworks have received increasing attention due to their regular pores and large surfaces. Typically

these periodic porous materials are solids that are not soluble or do not decompose upon being dissolved. Since 2013

our lab and several other groups have developed the strategy of self-assembly for constructing water-soluble periodic supramolecular organic frameworks (SOFs) from rationally designed molecular blocks. The most widely used binding motif for the generation of such regular supramolecular architectures involves cucurbit[8]uril (CB[8]

)-encapsulation-enhanced dimerization of two identical or different aromatic units in aqueous media. By attaching such hydrophobic aromatic units to a rigid triangular

tetrahedral

or octahedral core

tri-

tetra-

or hexa-armed building blocks have been prepared. By mixing these water-soluble precursors with CB[8] in a molar stoichiometry

two-dimensional (2D) honeycomb SOFs

three-dimensional (3D) diamondoid and cubic SOFs have been constructed. From porphyrin-and tetraphenylethene-cored planar tetra-armed precursors

2D square and rhombic SOFs have also been generated. For the formation of the porphyrin-based 2D SOF and one honeycomb 2D SOF

CB[8]

-encapsulation-enhanced donor-acceptor interaction between electron-rich dioxynaphthalene and electron-deficient viologen have been used as the driving force. For another honeycomb 2D SOF

dimerization of viologen radical cations has been used

without or with the encapsulation of CB[8]. The periodicity of both 2D and 3D SOFs has been supported by solution-phase synchrotron X-ray diffraction and scattering experiments. All the SOFs can also maintain the periodicity in their solid state and the pores of the 3D SOFs can be observed using high-resolution TEM. The 2D SOFs have all been revealed to be of monolayer by AFM. All multi-armed building blocks are positively charged and thus both 2D and 3D SOFs may be regarded as a new generation of regular supramolecular polyelectrolytes. One 2D SOF has been found to exhibit antimicrobial activity. The diamondoid 3D SOF exhibits highly efficient capacity of adsorbing anionic organic dye

drug

peptide

nucleic acid and dendrimer guests

while the cubic 3D SOF

the hexa-armed precursor of which contains a Ru(2

2'-bipyridine)

core

adsorbs hexaanionic Wells-Dawson-polyoxometallates (POMs). Under the irradiation of visible light (500 nm)

the ruthenium complex can sensitize the catalysis of adsorbed POMs in the reduction of proton into hydrogen gas in both homogeneous and heterogeneous manners. The review highlights the advances and

in the last section

provides future directions for new structures and functions.

关键词

超分子有机框架超分子聚合物多孔材料自组装周期性

Keywords

Supramolecular organic frameworkSupramolecular polymersPorous materialsSelf-assemblyPeriodicity

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