浏览全部资源
扫码关注微信
等规聚丙烯
β 晶型向α 晶型的相转变行为研究进展Research Progress on Phase Transformation Behavior of
β toα -Form Isotactic Polypropylene- 高分子学报 2017年第4期 页码：580-586
- 作者机构：
北京化工大学 化工资源有效利用国家重点实验室 北京 100029
- 作者简介：
李慧慧, E-mail:lihuihui@mail.buct.edu.cn Hui-hui Li, E-mail:lihuihui@mail.buct.edu.cn
- 基金信息：国家自然科学基金(21174014);国家自然科学基金(21374007)
DOI：10.11777/j.issn1000-3304.2017.16240
中图分类号：纸质出版日期：2017-4，
收稿日期：2016-7-31，
修回日期：2016-8-29，
扫 描 看 全 文
甄薇薇, 李慧慧, 闫寿科. 等规聚丙烯
β 晶型向α 晶型的相转变行为研究进展[J]. 高分子学报, 2017,(4):580-586.Wei-wei Zhen, Hui-hui Li, Shou-ke Yan. Research Progress on Phase Transformation Behavior of
β toα -Form Isotactic Polypropylene[J]. Acta Polymerica Sinica, 2017,(4):580-586.甄薇薇, 李慧慧, 闫寿科. 等规聚丙烯
β 晶型向α 晶型的相转变行为研究进展[J]. 高分子学报, 2017,(4):580-586. DOI： 10.11777/j.issn1000-3304.2017.16240.Wei-wei Zhen, Hui-hui Li, Shou-ke Yan. Research Progress on Phase Transformation Behavior of
β toα -Form Isotactic Polypropylene[J]. Acta Polymerica Sinica, 2017,(4):580-586. DOI： 10.11777/j.issn1000-3304.2017.16240.
摘要
等规聚丙烯（iPP）是典型的多晶型半结晶性聚合物，其常见晶型有单斜（
α
），三方（
β
），三斜（
γ
）以及四方或双四方（
e
），其中稳定性最好的
α
晶型和处于亚稳态的
β
晶型工业和经济价值较大，因此二者之间的相转变行为得到了人们的广泛关注.本文综述了近年来
β
→
α
-iPP生长相转变的研究进展.在高临界温度（141℃）和低临界温度（100 ℃）区间内，
β
-iPP生长速率高于
α
-iPP，而温度高于141 ℃，或低于100 ℃，由于
α
-iPP在动力学上占优势，
β
-iPP会发生向
α
-iPP的生长转变.但由于
α
-iPP是热力学上最稳定的晶型，
β
-iPP熔融重结晶过程也会发生
β
→
α
-iPP相转变.此外，拉伸形变过程中也会发生
β
→
α
-iPP相转变，广泛用于制备聚丙烯气体交换膜、过滤膜或锂电池隔膜等.目前对变形过程中的
β
→
α
-iPP相转变机理还存在争议，本文也对2种主要的机理进行了介绍，并对聚丙烯晶型转变行为的研究方向进行了展望.
Abstract
Isotactic polypropylene (iPP) is a semi-crystalline polymer which exhibits polymorphisms
designated respectively as monoclinic
α
-
trigonal
β
-
orthorhombic
γ
-and tetragonal
e
-form. Due to the industrial and economic value
α
-and
β
-iPP have been widely studied
and the transformation behavior between these two phases has been extensively investigated. Therefore
studies in recent years with the focus on such topic are generally reviewed in this article. Originally
the growth rate of
β
-iPP is over that of
α
-iPP between high critical temperature (141 ℃) and low critical temperature (100-105 ℃). But when the temperature is higher than 141 ℃ or lower than 100 ℃
β
→
α
-iPP phase transformation could occur
for
α
-iPP is kinetically favorable. This growth transformation can be realized by two-step crystallization of iPP. Besides
such phase transformation would take place during melting and recrystallization because
α
-iPP crystals are thermodynamically more stable. Moreover
the
β
→
α
-iPP phase transformation can also be observed during deformation at room temperature or high temperature
and microporous membranes can be prepared
via
this process due to the higher density of
α
-iPP. Such products could be used as gas exchange membrane
filter membrane or separator of lithium-ion batteries. Since the transformation mechanism during deformation is still controversial
the article also reviews two proposed ideas about it. One is that the transformation during stretching should experience partial melting and recrystallization
and the other is just a solid-solid phase transformation. In addition
there are problems remaining that should be further explored about the
β
→
α
-iPP phase transformation. For example
it is still unknown whether there is crystallographic relationship between new formed
α
-iPP and original
β
-iPP during two-step crystallization
or it is just realized by a nucleation process. So
this will be an appealing direction for researchers in the field of polymer physics.
关键词
等规聚丙烯α相等规聚丙烯β相等规聚丙烯相转变
Keywords
Isotactic polypropyleneα-Form isotactic polypropyleneβ-Form isotactic polypropylenePhase transformation
references
B Lotz , J C Wittmann , A Lovinger . Polymer , 1996 . 37 ( 22 ): 4979 - 4992 . DOI:10.1016/0032-3861(96)00370-9http://doi.org/10.1016/0032-3861(96)00370-9.
Chuanguo Ma , Minzhi Rong , Mingqiu Zhang . Acta Polymerica Sinica , 2003 . ( 3 ): 381 - 386 . http://www.gfzxb.org/CN/abstract/abstract9813.shtml.
马 传国 , 容 敏智 , 章 明秋 . 高分子学报 , 2003 . ( 3 ): 381 - 386 . http://www.gfzxb.org/CN/abstract/abstract9813.shtml.
Guixia Long , Shi Yang . Acta Polymerica Sinica , 1998 . ( 5 ): 532 - 535 . http://www.gfzxb.org/CN/abstract/abstract10653.shtml.
龙 桂霞 , 杨 始 . 高分子学报 , 1998 . ( 5 ): 532 - 535 . http://www.gfzxb.org/CN/abstract/abstract10653.shtml.
B Lotz . Macromolecules , 2014 . 47 ( 21 ): 7612 - 7624 . DOI:10.1021/ma5009868http://doi.org/10.1021/ma5009868.
H D Keith , F J Padden , N M Walter , H W Wyckoff . J Appl Phys , 1959 . 30 1485 - 1488 . DOI:10.1063/1.1734986http://doi.org/10.1063/1.1734986.
S V Meille , D R Ferro , S Brucker , A J Lovinger , F J Padden . Macromolecules , 1994 . 27 ( 9 ): 2615 - 2622 . DOI:10.1021/ma00087a034http://doi.org/10.1021/ma00087a034.
D L Dorset , M P McCourt , S Kopp , M Schumacher , T Okihara , B Lotz . Polymer , 1998 . 39 ( 8 ): 6331 - 6337.
B Lotz . J Macromol Sci, Part B: Physics , 2002 . 41 ( 4 ): 685 - 709 . DOI:10.1081/MB-120013059http://doi.org/10.1081/MB-120013059.
A J Lovinger , J O Chua , C C Gryte . J Polym Sci , 1977 . 15 ( 4 ): 641 - 656.
A Turner-Jones , A J Cobbold . J Polym Sci , 1968 . 6 ( 8 ): 539 - 546 . DOI:10.1002/pol.1968.110060802http://doi.org/10.1002/pol.1968.110060802.
P Jacoby , B H Bersted , W J Kissel , C E Smith . J Polym Sci , 1986 . 24 ( 3 ): 461 - 491 . DOI:10.1002/polb.1986.090240301http://doi.org/10.1002/polb.1986.090240301.
F L Binsbergen , B G M Delange . Polymer , 1970 . 11 ( 6 ): 309 - 326 . DOI:10.1016/0032-3861(70)90071-6http://doi.org/10.1016/0032-3861(70)90071-6.
J Garbarczyk , D Paukzta . Polymer , 1981 . 22 ( 4 ): 562 - 564 . DOI:10.1016/0032-3861(81)90182-8http://doi.org/10.1016/0032-3861(81)90182-8.
J Garbarczyk , D Paukzta . Colloid Polym Sci , 1985 . 263 ( 12 ): 985 - 990 . DOI:10.1007/BF01410991http://doi.org/10.1007/BF01410991.
K Nitta . J Polym Sci , 1999 . 37 ( 4 ): 357 - 368 . DOI:10.1002/(ISSN)1099-0488http://doi.org/10.1002/(ISSN)1099-0488.
Qing Chen , Yurun Fan , Qiang Zheng . Acta Polymerica Sinica , 2007 . ( 5 ): 467 - 471 . http://www.gfzxb.org/CN/abstract/abstract10405.shtml.
陈 青 , 范 毓润 , 郑 强 . 高分子学报 , 2007 . ( 5 ): 467 - 471 . http://www.gfzxb.org/CN/abstract/abstract10405.shtml.
Mingliang Ge , Demin Jia . Acta Polymerica Sinica , 2010 . ( 10 ): 1199 - 1203 . http://www.gfzxb.org/CN/abstract/abstract13077.shtml.
戈 明亮 , 贾 德民 . 高分子学报 , 2010 . ( 10 ): 1199 - 1203 . http://www.gfzxb.org/CN/abstract/abstract13077.shtml.
T Foresta , S Piccarolo , G Goldbeck-Wood . Polymer , 2001 . 42 ( 3 ): 1167 - 1176 . DOI:10.1016/S0032-3861(00)00404-3http://doi.org/10.1016/S0032-3861(00)00404-3.
G Natta , P Corradini . J Polym Sci , 1959 . 39 29 - 46 . DOI:10.1002/pol.1959.1203913504http://doi.org/10.1002/pol.1959.1203913504.
F J Padden , H D Keith . J Appl Phys , 1959 . 30 1479 - 1484 . DOI:10.1063/1.1734985http://doi.org/10.1063/1.1734985.
A J Lovinger , J O Chua , C C Gryte . J Polym Sci, Polym Phys Ed , 1977 . 15 ( 4 ): 641 - 656 . DOI:10.1002/pol.1977.180150405http://doi.org/10.1002/pol.1977.180150405.
J Varga , Y Fujiwara , A Ille . Period Polytech Chem Eng , 1990 . 34 ( 4 ): 255 - 271.
B Lotz . Polymer , 1998 . 39 ( 19 ): 4561 - 4567 . DOI:10.1016/S0032-3861(97)10147-1http://doi.org/10.1016/S0032-3861(97)10147-1.
B Lotz , B Fillon , A Therry , J C Wittmann . Polymer Bulletin , 1991 . 25 ( 1 ): 101 - 105.
B Lotz , J C Wittmann . Colloid Polym Sci , 1992 . 87 3 - 7.
B Fillon , A Therry , J C Wittmann , B Lotz . J Polym Sci, Polym Phys , 1993 . 31 ( 10 ): 1407 - 1427 . DOI:10.1002/polb.1993.090311015http://doi.org/10.1002/polb.1993.090311015.
K Nakamura , S Shimizu , S Umemoto , A Thierry , B Lotz , N Okui . Polymer , 2008 . 40 ( 9 ): 915 - 922 . DOI:10.1295/polymj.PJ2007231http://doi.org/10.1295/polymj.PJ2007231.
J Varga , G W Ehrenstein . Colloid Polym Sci , 1997 . 275 ( 6 ): 511 - 519 . DOI:10.1007/s003960050113http://doi.org/10.1007/s003960050113.
K Cho , D N Saheb , J Choi , H Yang . Polymer , 2002 . 43 ( 14 ): 1407 - 1416.
J Varga . J Mater Sci , 1992 . 27 ( 10 ): 2557 - 2579 . DOI:10.1007/BF00540671http://doi.org/10.1007/BF00540671.
Xiaodong Zhang , Guanyi Shi . Acta Polymerica Sinica , 1992 . ( 3 ): 293 - 299 . http://www.gfzxb.org/CN/abstract/abstract12727.shtml.
张 晓东 , 史 观一 . 高分子学报 , 1992 . ( 3 ): 293 - 299 . http://www.gfzxb.org/CN/abstract/abstract12727.shtml.
Jianyuan Pan , Chengshen Zhu , Shikun Yang , Rongyin Feng . Acta Polymerica Sinica , 1987 . ( 6 ): 432 - 436 . http://www.gfzxb.org/CN/abstract/abstract12089.shtml.
潘 鉴元 , 朱 诚身 , 杨 始堃 , 冯 榕荫 . 高分子学报 , 1987 . ( 6 ): 432 - 436 . http://www.gfzxb.org/CN/abstract/abstract12089.shtml.
C Mathieu , J C Wittmann , B Lotz , A Thierry . Polymer , 2000 . 41 ( 19 ): 7241 - 7253 . DOI:10.1016/S0032-3861(00)00062-8http://doi.org/10.1016/S0032-3861(00)00062-8.
E Jenckel , E Teege , W Hinrichs . Kolloid Zeitherft , 1952 . 129 19 - 24 . DOI:10.1007/BF01802755http://doi.org/10.1007/BF01802755.
Campbell , D , M M Qayyum . J Polym Sci, Polym Phys Ed , 1980 . 18 ( 1 ): 83 - 93 . DOI:10.1002/pol.1980.180180107http://doi.org/10.1002/pol.1980.180180107.
M R Kantz , R D Cornelliussen . J Polym Lett , 1973 . 11 ( 4 ): 279 - 284 . DOI:10.1002/pol.1973.130110414http://doi.org/10.1002/pol.1973.130110414.
M J Folkes , S T Hardwick . J Mater Sci Lett , 1987 . 6 ( 6 ): 656 - 658 . DOI:10.1007/BF01770916http://doi.org/10.1007/BF01770916.
H Li , J C Liu , S D Jiang , J J Wang , D J Wang , S Yan . Macromolecules , 2003 . 36 ( 8 ): 2802 - 2807 . DOI:10.1021/ma034062whttp://doi.org/10.1021/ma034062w.
H Li , X Zhang , J Kuang , D Wang , L Li , S Yan . Macromolecules , 2004 . 37 ( 8 ): 2847 - 2853 . DOI:10.1021/ma035932chttp://doi.org/10.1021/ma035932c.
H Li , X Zhang , Y Duan , D Wang , L Li , S Yan . Polymer , 2004 . 45 ( 23 ): 8059 - 8065 . DOI:10.1016/j.polymer.2004.09.032http://doi.org/10.1016/j.polymer.2004.09.032.
M Avella , G Della Volpe , E Martuscelli . J Polym Eng Sci , 1992 . 32 376 - 382.
M Avella , B Pascucci , E Martuscelli . J Polym Eng Sci , 1992 . 32 383 - 391.
D Trifonova , G J Vancso , J Varga . Polymer Bulletin , 1998 . 41 ( 3 ): 341 - 348 . DOI:10.1007/s002890050372http://doi.org/10.1007/s002890050372.
H Li , X Sun , S Yan , J M Schultz . Macromolecules , 2008 . 41 ( 13 ): 5062 - 5064 . DOI:10.1021/ma702725ghttp://doi.org/10.1021/ma702725g.
J Wang , Z Ren , X Sun , H Li , S Yan . Colloid Polym Sci , 2015 . 293 ( 10 ): 2823 - 2830 . DOI:10.1007/s00396-015-3599-3http://doi.org/10.1007/s00396-015-3599-3.
Haiping Xing , Yujie Wang , Dong Wan , Zhenjiang Zhang , Zhiwei Jiang , Tao Tang . Acta Polymerica Sinica , 2012 . ( 11 ): 1200 - 1217 . http://www.gfzxb.org/CN/abstract/abstract13808.shtml.
邢 海平 , 王 宇杰 , 万 东 , 张 振江 , 姜 治伟 , 唐 涛 . 高分子学报 , 2012 . ( 11 ): 1200 - 1217 . http://www.gfzxb.org/CN/abstract/abstract13808.shtml.
K Cho , D N Saheb , H Yang , B Kang , J Kim , S Lee . Polymer , 2003 . 44 ( 14 ): 4053 - 4059 . DOI:10.1016/S0032-3861(03)00305-7http://doi.org/10.1016/S0032-3861(03)00305-7.
Y Shang , J Zhao , J Li , Z Wu , S Jiang . Colloid Polym Sci , 2014 . 292 ( 12 ): 3205 - 3221 . DOI:10.1007/s00396-014-3368-8http://doi.org/10.1007/s00396-014-3368-8.
H Bai , Y Wang , Z Zhang , L Han , Y Li , L Liu , Z Zhou , Y Men . Macromolecules , 2009 . 42 ( 17 ): 6647 - 6655 . DOI:10.1021/ma9001269http://doi.org/10.1021/ma9001269.
A Turner-Jones , J M Aizlewood , D R Becket . Makromol Chem , 1964 . 75 134 - 158 . DOI:10.1002/macp.1964.020750113http://doi.org/10.1002/macp.1964.020750113.
T Asano , S D Z Cheng . Polymer , 1998 . 39 ( 19 ): 4461 - 4487 . DOI:10.1016/S0032-3861(97)10320-2http://doi.org/10.1016/S0032-3861(97)10320-2.
T Asano , Y Fujiwara , T Yoshida . Polymer , 1979 . 11 ( 5 ): 383 - 390 . DOI:10.1295/polymj.11.383http://doi.org/10.1295/polymj.11.383.
J Varga . J Thermal Anal , 1989 . 35 ( 6 ): 1891 - 1912 . DOI:10.1007/BF01911675http://doi.org/10.1007/BF01911675.
J Varga . J Thermal Anal , 1986 . 31 ( 1 ): 165 - 172 . DOI:10.1007/BF01913897http://doi.org/10.1007/BF01913897.
T Asano , Y Fujiwara . Polymer , 1978 . 19 ( 1 ): 99 - 108 . DOI:10.1016/0032-3861(78)90182-9http://doi.org/10.1016/0032-3861(78)90182-9.
J X Li , W L Cheung . Polymer , 1998 . 39 ( 26 ): 6935 - 6940 . DOI:10.1016/S0032-3861(98)00144-Xhttp://doi.org/10.1016/S0032-3861(98)00144-X.
J X Li , W L Cheung , C M Chan . Polymer , 1999 . 40 ( 13 ): 3641 - 3656 . DOI:10.1016/S0032-3861(98)00578-3http://doi.org/10.1016/S0032-3861(98)00578-3.
J X Li , W L Cheung . J Appl Polym Sci , 1999 . 72 ( 12 ): 1529 - 1538 . DOI:10.1002/(ISSN)1097-4628http://doi.org/10.1002/(ISSN)1097-4628.
T Yoshida , Y Fujiwara , T Asano . Polymer , 1983 . 24 ( 7 ): 925 - 929 . DOI:10.1016/0032-3861(83)90216-1http://doi.org/10.1016/0032-3861(83)90216-1.
G Y Shi , F Chu , G Zhou , Z Han . Makromol Chem , 1989 . 190 907 - 913 . DOI:10.1002/macp.1989.021900423http://doi.org/10.1002/macp.1989.021900423.
C Zhang , G Liu , Y Song , Y Zhao , D Wang . Polymer , 2014 . 55 ( 26 ): 6915 - 6923 . DOI:10.1016/j.polymer.2014.10.049http://doi.org/10.1016/j.polymer.2014.10.049.
Z Cai , Y Zhang , J Li , F Xue , Y Shang , X He , J Feng , Z Wu , S Jiang . Polymer , 2012 . 53 ( 7 ): 1593 - 1601 . DOI:10.1016/j.polymer.2012.02.012http://doi.org/10.1016/j.polymer.2012.02.012.
J Jia , W Mao , R Dierk . J Wuhan Uni Sci Tech, Nature Science Ed , 2007 . 30 ( 4 ): 360 - 363.
S N Rudnev , O B Salamation , V V Voenniy . Colloid Polym Sci , 1991 . 269 ( 5 ): 460 - 468 . DOI:10.1007/BF00655883http://doi.org/10.1007/BF00655883.
J Garbarczyk , T Sterzyski , D Paukzta . Polym Commun , 1989 . 30 ( 5 ): 153 - 157.
M Aboulfaraj , B Ulrich , A Dahoun . Polymer , 1993 . 34 ( 23 ): 4817 - 4825 . DOI:10.1016/0032-3861(93)90003-Shttp://doi.org/10.1016/0032-3861(93)90003-S.
W Xu , D C Martin , E M Arruda . Polymer , 1993 . 34 ( 23 ): 4817 - 4825 . DOI:10.1016/0032-3861(93)90003-Shttp://doi.org/10.1016/0032-3861(93)90003-S.
E Lezak , Z Bartczak , A Galeski . Polymer , 2006 . 47 ( 26 ): 8526 - 8574.
S Molnar , B Pukanszky , C O Hammer , F H J Maurer . Polymer , 2000 . 41 ( 4 ): 1529 - 1539 . DOI:10.1016/S0032-3861(99)00305-5http://doi.org/10.1016/S0032-3861(99)00305-5.
0
浏览量
10
下载量
2
CSCD
- BibTeX下载
- Endnote下载
- RefMan 下载
- NoteExpress下载
- NoteFirst下载
关联资源
相关文章
相关作者
相关机构
- 地址：北京中关村北一街2号（北京2709信箱） 邮编：100190
- 联系电话：010-62588927 Email：gfzxb@iccas.ac.cn
- 技术支持由北京北大方正电子有限公司提供 京ICP备05002797号-8
京公网安备11010802024621 - 本系统建议在Chrome、 IE9+ 以上版本浏览器阅读本站内容，360浏览器请切换至极速模式
- Cookies帮助我们提供服务并提供个性化体验。使用本网站，即表示您同意我们使用Cookies