浏览全部资源
扫码关注微信
适配双链与非适配单链包结
γ -CD聚准轮烷嵌段共聚物合成与表征Synthesis and Characterization of Matched Double-chain and Loose-fit Single-chain Stranded
γ -CD-based Polypseudorotaxane Containing- 高分子学报 2017年第8期 页码：1320-1330
- 作者机构：
北京理工大学材料学院 北京 100084
- 作者简介：
冯增国, E-mail:sainfeng@bit.edu.cn Zeng-guo Feng, E-mail:sainfeng@bit.edu.cn
- 基金信息：
DOI：10.11777/j.issn1000-3304.2017.16357
中图分类号：纸质出版日期：2017-8，
收稿日期：2016-12-13，
修回日期：2017-2-20，
扫 描 看 全 文
尤劼, 叶霖, 张爱英, 冯增国. 适配双链与非适配单链包结
γ -CD聚准轮烷嵌段共聚物合成与表征[J]. 高分子学报, 2017,(8):1320-1330.You Jie, Ye Lin, Zhang Ai-ying, Feng Zeng-guo. Synthesis and Characterization of Matched Double-chain and Loose-fit Single-chain Stranded
γ -CD-based Polypseudorotaxane Containing[J]. Acta Polymerica Sinica, 2017,(8):1320-1330.尤劼, 叶霖, 张爱英, 冯增国. 适配双链与非适配单链包结
γ -CD聚准轮烷嵌段共聚物合成与表征[J]. 高分子学报, 2017,(8):1320-1330. DOI： 10.11777/j.issn1000-3304.2017.16357.You Jie, Ye Lin, Zhang Ai-ying, Feng Zeng-guo. Synthesis and Characterization of Matched Double-chain and Loose-fit Single-chain Stranded
γ -CD-based Polypseudorotaxane Containing[J]. Acta Polymerica Sinica, 2017,(8):1320-1330. DOI： 10.11777/j.issn1000-3304.2017.16357.
摘要
首先在精准控制摩尔投料比条件下，通过缓慢加料方式制备出以2-溴异丁酰基为端基的双三缩四乙二醇偶氮苯二甲酸酯（Br-EG
4
-AZO-EG
4
-Br，
1
）作为引发剂，然后在[
γ
-CD]/[
1
]=4的条件下，将
1
与
γ
-环糊精（
γ
-CD）在水溶液中进行自组装制备得到双链包结聚准轮烷（iPPR），进而用该聚准轮烷原位引发N-异丙基丙烯酰胺（NIPAAm）进行原子转移自由基聚合（ATRP）得到聚准轮烷嵌段共聚物（PPRs）.分析结果表明，该类共聚物以
γ
-CD与偶氮苯和折叠三缩四乙二醇链自组装形成的适配双链包结结构的形式存在，而在与由
1
引发NIPAAm进行ATRP聚合所制备的PNIPAAm-EG
4
-AZO-EG
4
-PNIPAAm进行自组装包结时，
γ
-CD则均匀分布在整条共聚物链上生成非适配单链包结聚准轮烷嵌段共聚物（
a
PPRs）.与引发剂
1
和
a
PPRs相比，PPRs中代表反式偶氮苯基团的紫外吸收峰发生明显红移，但紫外光照射产生的顺式异构化几乎不导致
γ
-CD滑脱下链，说明
γ
-CD与偶氮苯和折叠三缩四乙二醇包结形成的适配双链包结结构不仅稳定性高，而且还能可逆地转化为
γ
-CD与双三缩四乙二醇链包结形式的适配双链包结结构.
Abstract
By carefully controlling the feeding ratio and slow feeding the reactants
2-bromoisobutyryl end-capped tetraethylene glycol azobenzene-4
4'-dicarboxylic ester (Br-EG
4
-AZO-EG
4
-Br
1
) was synthesized as an initiator. With
n
(
γ
-CD)/
n
(Br-EG
4
-AZO-EG
4
-Br)=4/1
the resulting initiator
1
was self-assembled with
γ
-cyclodextrin (
γ
-CD) in water to create first a double-chain stranded polypseudorotaxane (iPPR) as supramolecular initiator
which was then used to initiate
in situ
atom transfer radical polymerization (ATRP) of
N
-isopropylacrylamide (NIPAAm) to prepare polypseudorotaxane containing block copolymers (PPRs). It was found that the added
γ
-CDs accommodate both an azobenzene and a folded tetraethylene glycol chain in the block copolymers
presented as a matched double-chain stranded inclusion complexing structure. However
in the case of self-assembling with PNIPAAm-EG
4
-AZO-EG
4
-PNIPAAm prepared from ATRP of NIPAAm
γ
-CD was randomly distributed along the whole copolymer chain to give access to a series of loose-fit single-chain stranded inclusion complexing structured polypseudorotaxanes (
a
PPRs). Compared with Br-EG
4
-AZO-EG
4
-Br and
a
PPRs
the characteristic peak of ultraviolet (UV) absorption due to trans-azobenzene in PPRs was obviously red-shifted
but the unique cis-isomerization of this group appeared not leading to the threaded
γ
-CDs sliding off the polymeric chain. All these characterizations suggested that the matched double chain stranded inclusion complexing structure was constructed by an azobenzene and a folded tetraethylene glycol chain jointing to enter the cavity of
γ
-CD
showing not only a relatively higher stability
but also a reversible transformation into the double tetraethylene glycol chain stranded inclusion complexing structure in the process of cis-isomerization of the azobenzene.
关键词
偶氮苯嵌段共聚物γ-CD双链适配包结聚准轮烷
Keywords
AzobenzeneBlock copolymerγ-CDDouble-chain stranded inclusion complexing structurePolypseudorotaxane
references
J Szejtli . . Chem Rev , 1998 . 98 ( 5 ): 1743 - 1753 . DOI:10.1021/cr970022chttp://doi.org/10.1021/cr970022c.
Z Y Jing , X M Xu , H Q Chen , X H Li . Cyclodextrin Chemistry:Preparation and Application , : Beijing Chemical Industry Press , 2009 . 7 - 9.
Y Okumura , K Ito . . Adv Matter , 2001 . 13 ( 7 ): 485 - 487 . DOI:10.1002/(ISSN)1521-4095http://doi.org/10.1002/(ISSN)1521-4095.
J H Seo , S Kakinoki , N Yui . . Soft Matter , 2012 . 8 ( 20 ): 5477 - 5485 . DOI:10.1039/c2sm25318fhttp://doi.org/10.1039/c2sm25318f.
K Nishida , A Tamura , N Yui . . Polym Chem , 2015 . 6 ( 21 ): 4040 - 4047 . DOI:10.1039/C5PY00445Dhttp://doi.org/10.1039/C5PY00445D.
J Li , X Li , K C Toh . . Macromolecules , 2001 . 34 ( 26 ): 8829 - 8831 . DOI:10.1021/ma011129bhttp://doi.org/10.1021/ma011129b.
K A Udachin , L D Wilson , J A Ripmeester . . J Am Chem Soc , 2000 . 122 ( 49 ): 12375 - 12376 . DOI:10.1021/ja002189khttp://doi.org/10.1021/ja002189k.
B Mayer , C T Klein , I N Topchieva . . J Comput Aided Mol Des , 1999 . 13 ( 4 ): 373 - 383 . DOI:10.1023/A:1008095501870http://doi.org/10.1023/A:1008095501870.
P Gao , J Wang , ng Fe , G Z . . Macromol Chem Phys , 2011 . 212 ( 21 ): 2319 - 2327 . DOI:10.1002/macp.201100319http://doi.org/10.1002/macp.201100319.
Peng Gao , Peijing Wang , Xue Geng , Lin Ye , Aiying Zhang , Zengguo Feng . . Acta Chimica Sinica , 2013 . 71 ( 3 ): 347 - 350.
高 鹏 , 王 培境 , 耿 雪 , 叶 霖 , 张 爱英 , 冯 增国 . . 化学学报 , 2013 . 71 ( 3 ): 347 - 350.
K Nonaka , M Yamaguchi , M Yasui , S Fujiwara , T Hashimoto , T Hayashita . . Chem Commun , 2014 . 50 ( 70 ): 10059 - 10061 . DOI:10.1039/C4CC04227Ahttp://doi.org/10.1039/C4CC04227A.
Z F Liu , K Morigaki , K Hashimoto . . Anal Chem , 1992 . 64 ( 2 ): 134 - 137 . DOI:10.1021/ac00026a007http://doi.org/10.1021/ac00026a007.
Z F Liu , K Morigaki , K Hashimoto . . Nature , 1990 . 347 ( 6294 ): 658 - 660 . DOI:10.1038/347658a0http://doi.org/10.1038/347658a0.
Tao Sun , Yueming Li , Feifei Xin , Shangyang Li , Yuehui Hou , Aiyou Hao . . Progress in Chemistry , 2012 . 24 ( 1 ): 70 - 79.
孙 涛 , 李 月明 , 辛 飞飞 , 李 尚洋 , 侯 月会 , 郝 爱友 . . 化学进展 , 2012 . 24 ( 1 ): 70 - 79.
Q Bian , W S Wang , G J Wang . . ACS Appl Mat Interfaces , 2016 . 8 ( 40 ): 27360 - 27367 . DOI:10.1021/acsami.6b09734http://doi.org/10.1021/acsami.6b09734.
J Hu , A Hashidzume , A Harada . . Macromol Chem Phys , 2011 . 212 ( 10 ): 1032 - 1038 . DOI:10.1002/macp.v212.10http://doi.org/10.1002/macp.v212.10.
A Harada , H Adachi , Y Kawaguchi . . Macromolecules , 1997 . 30 ( 17 ): 5181 - 5182 . DOI:10.1021/ma970269bhttp://doi.org/10.1021/ma970269b.
A Hashidzume , A Harada . . Polymer , 2006 . 47 ( 10 ): 3448 - 3454 . DOI:10.1016/j.polymer.2006.03.040http://doi.org/10.1016/j.polymer.2006.03.040.
W Oi , A Hashidzume , A Harada . . Polymer , 2011 . 52 ( 3 ): 746 - 751 . DOI:10.1016/j.polymer.2010.12.027http://doi.org/10.1016/j.polymer.2010.12.027.
D Taura , A Hashidzume , A Harada . . Macromol Rapid Commun , 2007 . 28 ( 24 ): 2306 - 2310 . DOI:10.1002/(ISSN)1521-3927http://doi.org/10.1002/(ISSN)1521-3927.
D Taura , A Hashidzume , Y Okumura . . Macromolecules , 2008 . 41 ( 10 ): 3640 - 3645 . DOI:10.1021/ma800026hhttp://doi.org/10.1021/ma800026h.
L Giuseppe , O Gerd , A Viveka . . Soft Matter , 2012 . 8 ( 18 ): 5043 - 5054 . DOI:10.1039/c2sm07252ahttp://doi.org/10.1039/c2sm07252a.
S J Han , M K Yoo , Y K Sung . . Macromol Rapid Commun , 1998 . 19 ( 8 ): 403 - 407 . DOI:10.1002/(ISSN)1521-3927http://doi.org/10.1002/(ISSN)1521-3927.
A Takahashi , R Katoono , N Yui . . Macromolecules , 2009 . 42 ( 22 ): 8587 - 8589 . DOI:10.1021/ma9022372http://doi.org/10.1021/ma9022372.
J Wang , L Ye , A Y Zhang , Z G Feng . . J Mater Chem , 2011 . 21 ( 9 ): 3243 - 3250 . DOI:10.1039/C0JM02803Ghttp://doi.org/10.1039/C0JM02803G.
T Kong , L Ye , A Y Zhang , Z G Feng . . Beilstein J Org Chem , 2013 . 10 ( 1 ): 2461 - 2469.
J Wang , L Ye , A Y Zhang , Z G Feng . . Macromol Rapid Commun , 2012 . 33 ( 13 ): 1143 - 1148 . DOI:10.1002/marc.201200017http://doi.org/10.1002/marc.201200017.
A Harada , J Li , T Nakamitsu . . J Org Chem , 1993 . 58 ( 26 ): 7524 - 7528 . DOI:10.1021/jo00078a034http://doi.org/10.1021/jo00078a034.
A Harada , J Li , M Kamachi . . J Am Chem Soc , 1994 . 116 ( 8 ): 3192 - 3196 . DOI:10.1021/ja00087a004http://doi.org/10.1021/ja00087a004.
0
浏览量
14
下载量
0
CSCD
- 网络PDF下载
- BibTeX下载
- Endnote下载
- RefMan 下载
- NoteExpress下载
- NoteFirst下载
关联资源
相关文章
相关作者
相关机构
- 地址：北京中关村北一街2号（北京2709信箱） 邮编：100190
- 联系电话：010-62588927 Email：gfzxb@iccas.ac.cn
- 技术支持由北京北大方正电子有限公司提供 京ICP备05002797号-8
京公网安备11010802024621 - 本系统建议在Chrome、 IE9+ 以上版本浏览器阅读本站内容，360浏览器请切换至极速模式
- Cookies帮助我们提供服务并提供个性化体验。使用本网站，即表示您同意我们使用Cookies