Janus复合材料调控界面

梁福鑫; 杨振忠

doi:10.11777/j.issn1000-3304.2017.17012

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Janus复合材料调控界面

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- Janus复合材料调控界面
- Progress in Janus Composites toward Interfacial Engineering
- 高分子学报 2017年第6期页码：883-892
- 作者机构：
  
  中国科学院化学研究所高分子物理与化学国家重点实验室北京 100190
- 作者简介：
  
  [ "杨振忠, 男, 1968年5月生, 博士, 研究员, 现任中国科学院化学研究所高分子物理与化学国家重点实验室主任. 1991年于清华大学获得学士学位, 1994年于吉林大学获得硕士学位, 1997年于中国科学院化学研究所获得博士学位.主要从事微纳结构高分子复合功能体系合成方法学及物理与化学基本问题研究. 2003年获国家杰出青年科学基金, 2011年为纳米研究重大科学研究计划项目首席科学家, 2013年获国家自然科学二等奖(第一完成人), 2016年入选国家万人计划科技创新领军人才" ]
- 基金信息：
  
  国家自然科学基金(51233007);国家自然科学基金(51622308)
- DOI：10.11777/j.issn1000-3304.2017.17012
  中图分类号：
- 纸质出版日期：2017-6，
  
  收稿日期：2017-1-13，
  
  修回日期：2017-2-16，
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梁福鑫, 杨振忠. Janus复合材料调控界面[J]. 高分子学报, 2017,(6):883-892.

Fu-xin Liang, Zhen-zhong Yang. Progress in Janus Composites toward Interfacial Engineering[J]. Acta Polymerica Sinica, 2017,(6):883-892.
梁福鑫, 杨振忠. Janus复合材料调控界面[J]. 高分子学报, 2017,(6):883-892. DOI： 10.11777/j.issn1000-3304.2017.17012.

Fu-xin Liang, Zhen-zhong Yang. Progress in Janus Composites toward Interfacial Engineering[J]. Acta Polymerica Sinica, 2017,(6):883-892. DOI： 10.11777/j.issn1000-3304.2017.17012.

摘要

Janus材料集成不同组成/功能于一体，具有明确的空间分区特征，是一类特殊的高分子复合功能材料.有机高分子链提供亲水/亲油及响应特性，无机组成提供丰富的光、电、磁、热等功能性.两亲性的Janus材料在高效稳定界面同时，还能赋予界面功能性并可在外场作用下实现操控.本文重点总结了不同结构和功能的Janus材料在稳定界面和调控界面的近期主要进展，包括聚集行为、固体乳化剂、界面增容、界面催化、功能涂层、细胞诊断与治疗等方面.

Abstract

Janus is named after the Roman god who is depicted to have two opposite faces looking at the past and the future. In 1991

de Gennes introduced the Janus particles in his Nobel lecture. Janus materials have triggered extensive research interests in academia and industry. Janus composites possess two different chemical regions and functions that are distinctly compartmentalized onto the same object. While the organic polymer components provide tunable wettability and responsive performances

the inorganic (or metallic) components offer desired functionalities such as magnetic manipulation and light thermal effect. We have developed methods to precisely tune shape

size

microstructure and chemistry of Janus composites and therefore their performance. In analogy to molecular surfactants or copolymers

the amphiphilic Janus composites can stabilize interfaces more effectively. Similarly

the Janus composites can serve as emulsifiers in emulsion polymerization and as compatibilizers for polymer alloys. Moreover

the interfaces stabilized with the Janus composites can be easily manipulated by using external stimuli

and functionalized by delivering desired species thereby. By grafting responsive polymer chains

the emulsions can be de-stabilized by simple changing pH

temperature

light irradiation or exchanging of ions. When Janus composites contain paramagnetic species

the emulsion droplets can be withdrawn with a magnet. The droplets are further coalesced

leading to de-emulsification under a stronger magnetic field. This performance is important to remedy polluted water or soil with organic species in the presence of surfactants. By conjugation of heterogeneous catalysts onto the Janus composites

the catalytic efficiency of the catalysts is greatly enhanced. Functional species such as Fe

or Au nanoparticles (NPs) can be delivered toward an oil/water interface when these NPs are grafted with hydrophobic and thermally responsive chains such as PNIPAM at the opposite sides. The de-emulsification can be easily achieved under NIR irradiationeven when the continuous phase temperature is below the LCST of PNIPAM(~32 ℃). The performance is enhanced from an interactive interplay between the hyperthermia effect of nanoparticles and a thermal energy transfer to fast locally heat PNIPAM.This performance is promising in heterogeneous catalysis and recycling of expensive catalysts. Wettability of Janus composites can be significantly magnified by nanoscale roughness. Robust superhydrophobic coatings are easily fabricated by forming a self-assembled monolayer of coarsening Janus microparticles and catalytic crosslinking the intermediate epoxy resin adhesive. In this Review

recent progress in manipulation of interfaces by Janus composites is summarized

including in emulsions and polymer alloys

interfacial heterogeneous catalysis

functional coatings

cell diagnosis and therapy.

关键词

Janus复合材料两亲性功能界面

Keywords

JanusCompositesAmphiphilicFunctionalInterface

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