以离子液体为介质的纤维素加工与功能化

张金明; 武进; 余坚; 张晓程; 米勤勇; 张军

doi:10.11777/j.issn1000-3304.2017.17066

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以离子液体为介质的纤维素加工与功能化

专论 | 更新时间：2021-01-26

- 以离子液体为介质的纤维素加工与功能化
- Processing and Functionalization of Cellulose with Ionic Liquids
- 高分子学报 2017年第7期页码：1058-1072
- 作者机构：
  
  1.中国科学院化学研究所中国科学院分子科学科教融合卓越中心中国科学院工程塑料重点实验室北京 100190
  2.中国科学院大学北京 100049
- 作者简介：
  
  [ "张军, 男, 1969年4月生.中国科学院化学研究所研究员, 中国科学院大学岗位教授, 中国科学院工程塑料重点实验室副主任.1993年安徽师范大学大学化学系本科, 1996年哈尔滨工程大学应用化学系硕士(导师:赵书兰教授), 1999年大连理工大学高分子材料系博士(导师:蹇锡高教授).2014年国家杰出青年基金获得者, 2015年山东省首届泰山产业领军人才.获2013年度北京市科学技术一等奖和2009年度北京市科学技术二等奖.目前担任中国纤维素行业协会(CCIA)技术委员会副主任, 中国科学院分子科学中心学术委员会委员, 《Polymer International》(Wiley)和《高分子学报》编委.主要研究兴趣包括:天然高分子的加工与功能化改性; 纤维素化学与物理; 离子液体在高分子材料中的应用; 功能化聚合物复合材料; 新型聚合物纤维等" ]
- 基金信息：
  
  国家自然科学基金(51425307);国家自然科学基金(51573196);国家自然科学基金(21374126);国家自然科学基金(51273206);国家自然科学基金(21174151);国家自然科学基金(51103167);国家自然科学基金(50973124);国家自然科学基金(50873111);国家自然科学基金(50473058);国家自然科学基金(50103011);山东省泰山产业领军人才和北京市科学技术研究院创新团队计划(项目号IG201605N)
- DOI：10.11777/j.issn1000-3304.2017.17066
  中图分类号：
- 纸质出版日期：2017-7，
  
  收稿日期：2017-3-30，
  
  修回日期：2017-3-30，
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张金明, 武进, 余坚, 张晓程, 米勤勇, 张军. 以离子液体为介质的纤维素加工与功能化[J]. 高分子学报, 2017,(7):1058-1072.

Jin-ming Zhang, Jin Wu, Jian Yu, Xiao-cheng Zhang, Qin-yong Mi, Jun Zhang. Processing and Functionalization of Cellulose with Ionic Liquids[J]. Acta Polymerica Sinica, 2017,(7):1058-1072.
张金明, 武进, 余坚, 张晓程, 米勤勇, 张军. 以离子液体为介质的纤维素加工与功能化[J]. 高分子学报, 2017,(7):1058-1072. DOI： 10.11777/j.issn1000-3304.2017.17066.

Jin-ming Zhang, Jin Wu, Jian Yu, Xiao-cheng Zhang, Qin-yong Mi, Jun Zhang. Processing and Functionalization of Cellulose with Ionic Liquids[J]. Acta Polymerica Sinica, 2017,(7):1058-1072. DOI： 10.11777/j.issn1000-3304.2017.17066.

摘要

纤维素作为自然界中储量最大的天然高分子，被认为是未来世界能源与化工的主要原料.但由于分子链间存在丰富氢键网络以及高度结晶的聚集态结构特点，天然纤维素不熔化、难溶解，造成纤维素的加工极其困难，纤维素材料的传统生产工艺复杂且污染严重，极大限制了纤维素材料的广泛应用.近年来，人们发现一些特定结构的离子液体能够高效溶解纤维素，为纤维素的加工和功能化提供了新的多用途平台.本文从“溶解纤维素的离子液体、纤维素溶解机理与溶液性质、以离子液体制备再生纤维素材料和以离子液体为介质合成纤维素衍生物” 4个方面详细介绍了本课题组在此领域的研究进展.

Abstract

As the most abundant natural polymer on the earth

cellulose has been considered as the sustainable raw material of energy and chemical engineering in the future. However

because of the strong hydrogen bonding network

cellulose is unmeltable and insoluble in conventional solvents

which limits its wide utilization. Effective utilization of cellulose-based resources is becoming a hot spot in chemistry

chemical engineering and material science fields. Recently

certain ionic liquids exhibited excellent dissolving capability for cellulose

which provides a new and versatile platform for cellulose processing and functionalization. By using ionic liquids as the solvents

a variety of cellulose-based materials

including fibers

films

hydrogels

aerogels and composites have been fabricated successfully and efficiently. Among them

regenerated cellulose fibers and films with outstanding mechanical properties are being produced on the pilot scale. In addition

almost all conventional cellulose esters

a variety of novel and functional cellulose esters

especially partially and regioselectively substituted cellulose esters

and cellulose graft copolymers have been successfully synthesized using ionic liquids as reaction media. In this review article

we will summarize our research work on cellulose dissolution

processing

homogeneous derivatization and graft copolymerization with ionic liquids. We first introduce the ionic liquids with good capability for dissolving cellulose. Then

the dissolution mechanism and dissolution process of cellulose in ionic liquids

and the physical properties of cellulose/ionic liquidssolutions are also discussed. Based on the understanding of the dissolution and regeneration process of cellulose in ionic liquids

our research progress on preparation of various regenerated cellulose-based materials in ionic liquids are described. The homogeneous derivatization and graft copolymerization of cellulose to make novel functional cellulose materials are also summarized. Finally

a brief outlook for future opportunities in advancing this area is also depicted. It is hoped that this review will draw more attention of scientists and engineers to this relatively new and exciting research field.

关键词

纤维素离子液体溶解再生衍生化

Keywords

CelluloseIonic liquidsDissolutionRegenerationDerivatization

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