水/醇溶共轭聚合物界面材料及其在光电器件中的应用

张凯; 黄飞; 曹镛

doi:10.11777/j.issn1000-3304.2017.17075

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水/醇溶共轭聚合物界面材料及其在光电器件中的应用

专论 | 更新时间：2021-01-27

- 水/醇溶共轭聚合物界面材料及其在光电器件中的应用
- Water/Alcohol Soluble Conjugated Polymer Interlayer Materials and Their Application in Solution Processed Multilayer Organic Optoelectronic Devices
- 高分子学报 2017年第9期页码：1400-1414
- 作者机构：
  
  发光材料与器件国家重点实验室高分子光电材料与器件研究所华南理工大学广州 510641
- 作者简介：
  
  [ "黄飞，男，1979年11月生.华南理工大学材料学院教授、博士生导师，发光材料与器件国家重点实验室副主任. 1996 ~ 2000年就读于北京大学化学与分子工程学院，获学士学位. 2000 ~ 2005年就读于华南理工大学材料科学与工程学院，获材料学博士学位. 2005 ~ 2009年在美国西雅图华盛顿大学材料系从事博士后研究. 2009年作为引进人才加入华南理工大学. 2011年获得国家自然科学基金委员会杰出青年基金的支持. 2011年获得中国化学会青年化学奖. 2013年入选首批科技部中青年科技创新领军人才. 2016年获聘教育部长江学者特聘教授.主要从事有机电子材料与器件方面的研究，内容涉及聚合物太阳电池、聚合物电致发光器件以及生物化学传感器等多个交叉学科领域" ]
  [ "曹镛，男，1941年10月生.华南理工大学材料学院教授，博士生导师，中国科学院院士. 1965年毕业于前苏联列宁格勒大学化学系，1987年获日本东京大学博士学位. 1988年被国务院学位委员会批准为博士生导师. 1988年至1990年在美国加州大学圣巴巴拉分校做访问研究. 1990年至1998年任美国UNIAX公司资深研究员. 1998年回国后加入华南理工大学. 2001年当选为中国科学院院士. 2008年当选发展中国家科学院(TWAS)院士.主要研究方向为聚合物光电材料与器件" ]
- 基金信息：
  
  国家自然科学基金(21634004)
- DOI：10.11777/j.issn1000-3304.2017.17075
  中图分类号：
- 纸质出版日期：2017-9，
  
  收稿日期：2017-4-5，
  
  修回日期：2017-5-11，
扫描看全文
张凯, 黄飞, 曹镛. 水/醇溶共轭聚合物界面材料及其在光电器件中的应用[J]. 高分子学报, 2017,(9):1400-1414.

Kai Zhang, Fei Huang, Yong Cao. Water/Alcohol Soluble Conjugated Polymer Interlayer Materials and Their Application in Solution Processed Multilayer Organic Optoelectronic Devices[J]. Acta Polymerica Sinica, 2017,(9):1400-1414.
张凯, 黄飞, 曹镛. 水/醇溶共轭聚合物界面材料及其在光电器件中的应用[J]. 高分子学报, 2017,(9):1400-1414. DOI： 10.11777/j.issn1000-3304.2017.17075.

Kai Zhang, Fei Huang, Yong Cao. Water/Alcohol Soluble Conjugated Polymer Interlayer Materials and Their Application in Solution Processed Multilayer Organic Optoelectronic Devices[J]. Acta Polymerica Sinica, 2017,(9):1400-1414. DOI： 10.11777/j.issn1000-3304.2017.17075.

摘要

相对于传统的无机半导体器件，以有机半导体（特别是聚合物半导体）材料为基础的有机光电器件，可采用与传统印刷技术（例如喷墨打印、卷对卷印刷等）相结合的溶液加工方式制备低成本、大面积、柔性光电器件，因而成为广泛关注的焦点，并得到了快速发展.实现溶液加工的高效有机光电器件的一个关键问题是界面问题——如何避免溶液加工时有机层间的互溶以及如何实现可印刷稳定金属电极的高效电子注入等.水/醇溶性共轭聚合物的迅速发展为解决溶液加工多层有机光电器件所面临的界面问题提供了有效手段.研究发现，水/醇溶共轭聚合物不但可以有效避免溶液加工多层器件中的界面互溶，而且还可与高功函数的稳定金属发生界面偶极相互作用而增强其电子注入，从而解决了高功函数稳定金属电子注入的难题，为实现全溶液加工的高效印刷有机光电器件提供了可行的方案.本文介绍了近年来本课题组在水/醇溶共轭聚合物阴极界面材料及器件应用方面的研究进展，并对水/醇溶共轭聚合物阴极界面材料在聚合物发光二极管和聚合物太阳电池中的工作机理进行了探讨.

Abstract

Comparing with traditional inorganic semiconductor devices

the organic optoelectronic devices based on organic semiconductors

especially polymer semiconductors

exhibit several distinct advantages

such as low cost

light weight

solution processibility

flexibility and compatibility with roll-to-roll printing

etc

and have drawn much attention from both academic and industrial fields. To fulfil solution processed high performance organic optoelectronic devices

one of the major challenges is to avoid interface erosion during solution processing as well as to improve the electron injection/extraction between printable high work function metals and active layers. Water/alcohol soluble conjugated polymers (WSCPs)

which are composed of conjugated backbones and highly polar side chains

can be processed from water

alcohol and other polar solvents. The unique solubility of WSCPs provide them with good opportunities to fabricate multilayer organic optoelectronic devices without interface mixing by solution processing

and it is found that WSCPs exhibit promising interface modification capability for high work function metal and/or metal oxide electrodes

which can greatly enhance the performance of organic optoelectronic devices. In this feature article

we gave an overview of our design strategies and achievements on WSCPs

including neutral amine based WSCPs and their quaternized derivatives

WSCPs without mobile counterions

cross-linkable WSCPs

WSCPs towards large area module device

and their applications as interface modification layers in solution processed highly efficient multilayer organic optoelectronic devices. A brief induction and discussion on working mechanisms of WSCPs serving as cathode modification layers in polymer light-emitting diodes (PLEDs) and polymer solar cells (PSCs) were also provided. The excellent cathode modification capability of WSCPs can be ascribed to:(a) WSCPs decrease the work function of cathode to increase the build in potential of devices as well as increase the open voltage (

); (b) WSCPs dope contacted PCBM at the interface to increase the conductivity and improve short-circuit current density (

); (c) WSCPs exhibit excellent electron-extraction and hole-blocking properties at the interface and increase the fill factor (FF).

关键词

水/醇溶共轭聚合物阴极界面修饰溶液加工聚合物发光二极管聚合物太阳电池

Keywords

Water/alcohol soluble conjugated polymerCathode interlayerSolution processingPolymer light-emitting diodePolymer solar cell

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