石墨烯基光子晶体纤维的制备及性能调控

孟佳意; 李昕; 龚龑; 王锐; 郑一平; 张德权

doi:10.11777/j.issn1000-3304.2017.17113

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石墨烯基光子晶体纤维的制备及性能调控

研究论文 | 更新时间：2021-01-26

- 石墨烯基光子晶体纤维的制备及性能调控
- Preparation and Performance Adjustment of Graphene-based Photonic Crystal Fibers
- 高分子学报 2018年第3期页码：389-394
- 作者机构：
  
  北京服装学院材料科学与工程学院服装材料研究开发与评价北京市重点实验室北京 100029
- 作者简介：
  
  李昕, E-mail: clylx@bift.edu.cnXin Li, E-mail: clylx@bift.edu.cn
- 基金信息：
  
  北京市教委科技重点项目(KZ201410012017);国家自然科学基金(21544002)
- DOI：10.11777/j.issn1000-3304.2017.17113
  中图分类号：
- 纸质出版日期：2018-3-20，
  
  收稿日期：2017-4-27，
  
  修回日期：2017-6-14，
扫描看全文
孟佳意, 李昕, 龚龑, 王锐, 郑一平, 张德权. 石墨烯基光子晶体纤维的制备及性能调控[J]. 高分子学报, 2018,(3):389-394.

Jia-yi Meng, Xin Li, Yan Gong, Rui Wang, Yi-ping Zheng, De-quan Zhang. Preparation and Performance Adjustment of Graphene-based Photonic Crystal Fibers[J]. Acta Polymerica Sinica, 2018,(3):389-394.
孟佳意, 李昕, 龚龑, 王锐, 郑一平, 张德权. 石墨烯基光子晶体纤维的制备及性能调控[J]. 高分子学报, 2018,(3):389-394. DOI： 10.11777/j.issn1000-3304.2017.17113.

Jia-yi Meng, Xin Li, Yan Gong, Rui Wang, Yi-ping Zheng, De-quan Zhang. Preparation and Performance Adjustment of Graphene-based Photonic Crystal Fibers[J]. Acta Polymerica Sinica, 2018,(3):389-394. DOI： 10.11777/j.issn1000-3304.2017.17113.

摘要

利用无皂乳液聚合法合成了单分散聚苯乙烯（PS）微球，以通过湿法纺丝自制的石墨烯纤维为基材，利用电泳沉积法在纤维表面沉积PS微球形成光子晶体纤维，通过改变微球粒径来控制纤维的颜色，并利用扫描电子显微镜、光学显微镜、紫外反射光谱和色度分析对光子晶体纤维进行了表征.结果表明，制备得到的PS微球表面光滑，形状规整并以六方密堆积形式在石墨烯纤维表面紧密有序排列，呈现壳芯结构.粒径为198、233和287 nm的PS微球分别得到了蓝、绿、紫红3种颜色的结构色纤维，所得光子晶体纤维的光子禁带分别位于471、547 nm，以及670和398 nm，与其颜色相吻合.采用CIE

xyY

色彩空间辨别所得光子晶体纤维颜色，蓝、绿、紫红3种颜色的明度因数分别为：15.96、29.72、3.85，其对应于纯蓝色、纯绿色、纯紫色明度值的44%、63%和32%，说明其具有较高的明度.计算得到蓝色、绿色、紫红色纤维饱和度分别为63%、59%、60%，由此可知3种不同颜色的纤维均具有较高饱和度.

Abstract

Mono-disperse polystyrene (PS) microspheres with different particle sizes were synthesized by soap-free emulsion polymerization

and deposited for the first time by electrophoretic deposition on the surface of the self-made graphene fibers prepared by wet spinning

and photonic crystal fibers with different structural colors were finally obtained

and characterized by SEM

optical microscopy

UV reflection spectra and colorimetric analysis. The results showed that the three PS microspheres

with diameters of 198

233 and 287 nm

respectively

were of smooth surface and uniform particle size with monodispersion coefficient less than 5%. After electrophoretic deposition

they were orderly aligned on the surface of graphene fibers as hexagonal close packing with a core-shell structure

forming photonic crystal fibers with different colors including blue

green and purplish red. Moreover

the photonic bandgaps of the three photonic crystal fibers were located at 471

547

670 and 398 nm

respectively

consistent with their colors. Calculated with Bragg's law

the reflection peaks of the photonic crystal fibers made from PS microspheres with 198 and 233 nm located at 474 and 558 nm

respectively

which are close to their experimental results. While the reflection peak of the photonic crystal fiber made from PS microspheres of 287 nm size was found at 687 nm

close to the longer wave peak of the experimental results. The CIE

xyY

color space was used to identify the color of the photonic crystal fibers. It was found that the brightness factors of blue

green

and purplish red photonic crystal fibers were 15.96

29.72 and 3.85

respectively

which corresponded to 44%

63% and 32% of pure blue

green and purple lightness

indicating that they all were of high brightness. Furthermore

the calculated saturation values of the blue

green

purplish red photonic crystal fibers were 63%

59% and 60%

respectively

showing that they all had a high degree of saturation. The photonic crystal fibers do not need dyeing and their colors never fade

which meet the requirements of green and environmental protection

presenting broad prospect for their applications.

关键词

聚苯乙烯微球石墨烯纤维电泳沉积光子晶体纤维结构色

Keywords

Polystyrene microsphereGraphene fibersElectrophoretic depositionPhotonic crystal fibersStructural color

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